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Brønsted Acid/Lewis Base Hybrid Complexes
http://hdl.handle.net/2237/00028557
http://hdl.handle.net/2237/0002855702260d76-c16c-46ef-adb6-80c8df0561f9
名前 / ファイル | ライセンス | アクション |
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chapter (3.7 MB)
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Item type | 図書の一部 / Book Chapter(1) | |||||
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公開日 | 2018-09-11 | |||||
タイトル | ||||||
タイトル | Brønsted Acid/Lewis Base Hybrid Complexes | |||||
言語 | en | |||||
著者 |
Hatano, Manabu
× Hatano, Manabu× Ishihara, Kazuaki |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Acid–base catalyst | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | BINOL | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Boron | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Magnesium | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Supramolecular catalyst | |||||
抄録 | ||||||
内容記述 | Recent progress on our Brønsted acid/Lewis base hybrid complexes in some asymmetric catalyses is reviewed. Based on the rational design of conjugated acid–base catalysts, tailor-made supramolecular catalysts can show remarkable catalytic activity and higher-ordered selectivities that cannot be realized by ready-made single-molecule catalysts. The chiral supramolecular magnesium(II) binaphtholate complexes trigger the highly enantioselective 1,4-hydrophosphinylation and 1,2-hydrophosphonylation of α,β-unsaturated carbonyl compounds, direct Mannich-type reaction, and hetero-Diels–Alder reaction. Moreover, the advanced supramolecular catalysts are prepared in situ from chiral 3,3′-disubstituted binaphthols and biphenols, arylboronic acid, and B(C6F5)3, for promoting the anomalous endo-/exo-selective Diels–Alder reaction. The specific mechanism and deep insights into the possible key intermediates are discussed on the basis of rational design of chiral supramolecular Brønsted acid/Lewis base hybrid catalysts as artificial enzymes. | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | First Online: 11 August 2015. | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
出版者 | Springer | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_3248 | |||||
タイプ | book part | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1007/3418_2015_143 | |||||
ISBN | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | ISBN | |||||
関連識別子 | 978-3-319-70804-1 | |||||
ISSN | ||||||
関連タイプ | isPartOf | |||||
識別子タイプ | ISSN | |||||
関連識別子 | 1436-6002 | |||||
図書名 | ||||||
図書名 | Chiral Lewis Acids | |||||
書誌情報 |
巻 62, p. 91-120, 発行日 2018 |
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著者版フラグ | ||||||
値 | author | |||||
シリーズ | ||||||
関連名称 | Topics in Organometallic Chemistry book series (TOPORGAN, volume 62) |