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Synthesis of A Pincer-IrV Complex with A Base-Free Alumanyl Ligand and Its Application toward the Dehydrogenation of Alkanes
http://hdl.handle.net/2237/00031023
http://hdl.handle.net/2237/00031023fb315670-b731-4179-8f58-d869c40e846e
名前 / ファイル | ライセンス | アクション |
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Text_20190809 (729.6 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2019-12-19 | |||||
タイトル | ||||||
タイトル | Synthesis of A Pincer-IrV Complex with A Base-Free Alumanyl Ligand and Its Application toward the Dehydrogenation of Alkanes | |||||
言語 | en | |||||
著者 |
Morisako, Shogo
× Morisako, Shogo× Watanabe, Seiya× Ikemoto, Satoru× Muratsugu, Satoshi× Tada, Mizuki× Yamashita, Makoto |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | This is the peer reviewed version of the following article: [S. Morisako, S. Watanabe, S. Ikemoto, S. Muratsugu, M. Tada, M. Yamashita, Angew. Chem. Int. Ed. 2019, 58, 15031.], which has been published in final form at [https://doi.org/10.1002/anie.201909009]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | alumanyl ligands | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | homogeneous catalysis | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | iridium | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | pincer complex | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | XANES | |||||
抄録 | ||||||
内容記述 | A pincer‐iridium complex bearing a Lewis‐base‐free X‐type alumanyl ligand has been synthesized. X‐ray diffraction, NMR and IR spectroscopy, as well as XANES analysis confirmed its tetrahydrido‐Ir^V structure and Lewis acidity at the Al center as supported by DFT calculations. The resulting complex was applied as a catalyst for the transfer dehydrogenation of cyclooctane. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | Wiley | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1002/anie.201909009 | |||||
ISSN(print) | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 14337851 | |||||
書誌情報 |
en : Angewandte Chemie International Edition 巻 58, 号 42, p. 15031-15035, 発行日 2019-10-14 |
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著者版フラグ | ||||||
値 | author |