WEKO3
アイテム
{"_buckets": {"deposit": "34130c47-8dad-4318-8d19-ebc4f9c76aa3"}, "_deposit": {"id": "29316", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "29316"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00029316", "sets": ["1941"]}, "author_link": ["96000", "96001", "96002", "96003", "96004", "96005", "96006", "96007", "96008", "96009", "96010", "96011", "96012", "96013"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2019-10-23", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "42", "bibliographicPageEnd": "16558", "bibliographicPageStart": "16553", "bibliographicVolumeNumber": "141", "bibliographic_titles": [{"bibliographic_title": "Journal of the American Chemical Society", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "High efficiency perovskite solar cells have underpinned the rapid growth of the field. However, their low device stability limits further advancement. Hygroscopic lithium bis(trifluoromethanesulfonyl)imide (Li^+TFSI^–) and metal electrode are the main causes of the device instability. In this work, the redox reaction between lithium-ion endohedral fullerenes and 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenylamine)-9,9′-spirobi-fluorene (spiro-MeOTAD) was controlled to optimize the amount of oxidized spiro-MeOTAD and antioxidizing neutral endohedral fullerenes. Application of this mixture to metal-free carbon nanotube (CNT)-laminated perovskite solar cells resulted in 17.2% efficiency with a stability time of more than 1100 h under severe conditions (temperature = 60 °C, humidity = 70%). Such high performance is attributed to the uninhibited charge flow, no metal-ion migration, and the enhanced antioxidizing activity of the devices.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "ファイル公開:2020-10-23", "subitem_description_language": "ja", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/jacs.9b06418", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Journal of the American Chemical Society], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-xJzrWDW3Dsxtz4c5gPGA].”", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN(print)", "attribute_value_mlt": [{"subitem_source_identifier": "0002-7863", "subitem_source_identifier_type": "PISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Jeon, Il", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "96000", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shawky, Ahmed", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "96001", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Lin, Hao-Sheng", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "96002", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Seo, Seungju", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "96003", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okada, Hiroshi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "96004", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Lee, Jin-Wook", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "96005", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Pal, Amrita", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "96006", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tan, Shaun", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "96007", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Anisimov, Anton", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "96008", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kauppinen, Esko I.", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "96009", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yang, Yang", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "96010", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Manzhos, Sergei", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "96011", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Maruyama, Shigeo", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "96012", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Matsuo, Yutaka", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "96013", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-10-23"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "LiC60TFSI CNT MS JACS revised 2.pdf", "filesize": [{"value": "4.4 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 4400000.0, "url": {"label": "LiC60TFSI CNT MS JACS revised 2", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/29316/files/LiC60TFSI CNT MS JACS revised 2.pdf"}, "version_id": "f941dbb9-2cd2-403a-bb41-48938eac4f31"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "Endohedral Fullerene", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Metallofullerene", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Carbon Nanotube", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Perovskite Solar Cells", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Stability of Solar Cells", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Controlled Redox of Lithium-Ion Endohedral Fullerene for Efficient and Stable Metal Electrode-Free Perovskite Solar Cells", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Controlled Redox of Lithium-Ion Endohedral Fullerene for Efficient and Stable Metal Electrode-Free Perovskite Solar Cells", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["1941"], "permalink_uri": "http://hdl.handle.net/2237/00031503", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2020-02-13"}, "publish_date": "2020-02-13", "publish_status": "0", "recid": "29316", "relation": {}, "relation_version_is_last": true, "title": ["Controlled Redox of Lithium-Ion Endohedral Fullerene for Efficient and Stable Metal Electrode-Free Perovskite Solar Cells"], "weko_shared_id": -1}
Controlled Redox of Lithium-Ion Endohedral Fullerene for Efficient and Stable Metal Electrode-Free Perovskite Solar Cells
http://hdl.handle.net/2237/00031503
http://hdl.handle.net/2237/00031503eb8a9630-3709-4645-9bf9-0e0032222cae
名前 / ファイル | ライセンス | アクション |
---|---|---|
LiC60TFSI CNT MS JACS revised 2 (4.4 MB)
|
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2020-02-13 | |||||
タイトル | ||||||
タイトル | Controlled Redox of Lithium-Ion Endohedral Fullerene for Efficient and Stable Metal Electrode-Free Perovskite Solar Cells | |||||
言語 | en | |||||
著者 |
Jeon, Il
× Jeon, Il× Shawky, Ahmed× Lin, Hao-Sheng× Seo, Seungju× Okada, Hiroshi× Lee, Jin-Wook× Pal, Amrita× Tan, Shaun× Anisimov, Anton× Kauppinen, Esko I.× Yang, Yang× Manzhos, Sergei× Maruyama, Shigeo× Matsuo, Yutaka |
|||||
アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Journal of the American Chemical Society], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-xJzrWDW3Dsxtz4c5gPGA].” | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Endohedral Fullerene | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Metallofullerene | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Carbon Nanotube | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Perovskite Solar Cells | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Stability of Solar Cells | |||||
抄録 | ||||||
内容記述 | High efficiency perovskite solar cells have underpinned the rapid growth of the field. However, their low device stability limits further advancement. Hygroscopic lithium bis(trifluoromethanesulfonyl)imide (Li^+TFSI^–) and metal electrode are the main causes of the device instability. In this work, the redox reaction between lithium-ion endohedral fullerenes and 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenylamine)-9,9′-spirobi-fluorene (spiro-MeOTAD) was controlled to optimize the amount of oxidized spiro-MeOTAD and antioxidizing neutral endohedral fullerenes. Application of this mixture to metal-free carbon nanotube (CNT)-laminated perovskite solar cells resulted in 17.2% efficiency with a stability time of more than 1100 h under severe conditions (temperature = 60 °C, humidity = 70%). Such high performance is attributed to the uninhibited charge flow, no metal-ion migration, and the enhanced antioxidizing activity of the devices. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | ファイル公開:2020-10-23 | |||||
言語 | ja | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | ACS Publications | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1021/jacs.9b06418 | |||||
ISSN(print) | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 0002-7863 | |||||
書誌情報 |
en : Journal of the American Chemical Society 巻 141, 号 42, p. 16553-16558, 発行日 2019-10-23 |
|||||
著者版フラグ | ||||||
値 | author |