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Molecular Structure of the S2 State with a g=5 Signal in the Oxygen Evolving Complex of Photosystem II
http://hdl.handle.net/2237/00032506
http://hdl.handle.net/2237/0003250665b22890-be6b-4a14-916e-a655a39a2a3a
名前 / ファイル | ライセンス | アクション |
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g48_manuscript (821.3 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2020-07-13 | |||||
タイトル | ||||||
タイトル | Molecular Structure of the S2 State with a g=5 Signal in the Oxygen Evolving Complex of Photosystem II | |||||
言語 | en | |||||
著者 |
Taguchi, Shota
× Taguchi, Shota× Noguchi, Takumi× Mino, Hiroyuki |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [The Journal of Physical Chemistry B], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-U8VEDEVIQ7JX9DFIQUGY].” | |||||
抄録 | ||||||
内容記述 | The g-factor shift of the g=4.1 EPR signal was detected in spinach PsbO/P/Q-depleted PS II. The effective g-factor of the signal shifts up to ∼4.9, depending on the Ca^2+ concentration. Hyperfine structure spacing with about 3 mT was detected in this g = 5 (4.9) signal. The shift to g = 5 (4.9) was related to the distortion of the manganese cluster, derived from the modification of the chemical bond or the crystalline field of the Mn4(III) in the manganese cluster. Based on the EPR analysis of the g = 5 (4.9) spin state, another molecular structure of the S2 state, a “distant Mn” structure, was discussed as an intermediate state between the S2 and S3 states. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | ファイル公開:2021-07-09 | |||||
言語 | ja | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | ACS Publications | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1021/acs.jpcb.0c02913 | |||||
ISSN(print) | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 1520-6106 | |||||
書誌情報 |
en : The Journal of Physical Chemistry B 巻 124, 号 27, p. 5531-5537, 発行日 2020-07-09 |
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著者版フラグ | ||||||
値 | author |