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2023-01-16T03:49:53Z
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The statistical mechanics of the electro-acoustic effects of liquids
Yamaguchi, T.
Matsuoka, T.
Koda, S.
open access
Copyright (2003) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.
The ultrasonic vibration potential (UVP) and the electrokinetic sonic amplitude (ESA) are described in terms of equilibrium time-correlation functions using the linear response theory. The reciprocal relationship between UVP and ESA is shown based on the formulation. By introducing the generalized Langevin theory and taking the hydrodynamic limit, it is discussed how the effective volume of ions in the UVP measurement is related to their partial molar thermodynamic quantities. The effective volume is proven exactly equal to the isothermal partial molar volume in the isothermal formulation. The effect of the adiabaticity of sound wave is also investigated.
American Institute of Physics
2003-08-22
eng
journal article
VoR
http://hdl.handle.net/2237/7062
https://nagoya.repo.nii.ac.jp/records/5457
https://doi.org/10.1063/1.1592797
0021-9606
The Journal of Chemical Physics
119
8
4437
4448
https://nagoya.repo.nii.ac.jp/record/5457/files/JChemPhys_119_4437.pdf
application/pdf
163.3 kB
2018-02-19