2024-03-28T23:56:17Z
https://nagoya.repo.nii.ac.jp/oai
oai:nagoya.repo.nii.ac.jp:00022884
2023-01-16T04:12:26Z
1903:1904:1905
Total Synthesis of (−)-Cardiopetaline
Nishiyama, Yoshitake
Yokoshima, Satoshi
Fukuyama, Tohru
open access
“This document is the Accepted Manuscript version of a Published Work that appeared in final form in<br/>[Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher.<br/>To access the final edited and published work see [http://pubs.acs.org/doi/abs/10.1021/acs.orglett.6b00789].”
The total synthesis of (−)-cardiopetaline, an aconitine-type natural product, has been accomplished. Our synthesis involved a Wagner–Meerwein rearrangement of a sulfonyloxirane that enabled, in a single step, the construction of the bicyclo[3.2.1] system in the aconitine skeleton and effective introduction of oxygen functional groups at the appropriate positions.
ACS Publications
2016-05-20
eng
journal article
AM
http://hdl.handle.net/2237/25052
https://nagoya.repo.nii.ac.jp/records/22884
https://doi.org/10.1021/acs.orglett.6b00789
1523-7060
Organic Letters
18
10
2359
2362
https://nagoya.repo.nii.ac.jp/record/22884/files/20160318_OL_YN160428.pdf
application/pdf
859.0 kB
2017-05-20