2024-03-29T10:53:56Z
https://nagoya.repo.nii.ac.jp/oai
oai:nagoya.repo.nii.ac.jp:00026254
2023-01-16T04:16:46Z
320:321:322
Synthesis and Application of Pyrrole-Based PNP–Ir Complexes to Catalytic Transfer Dehydrogenation of Cyclooctane
Nakayama, Shin
Morisako, Shogo
Yamashita, Makoto
open access
“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organometallics], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-FK8kCAWCWubxpiMidYz9].”
A series of tBu- and iPr-substituted PNP–pincer Ir and Rh complexes with pyrrole-based core were synthesized and characterized. The structures of the obtained complexes were varied depending on the size of alkyl substituents and ligands other than PNP ligand. All of them exhibit low activity toward transfer dehydrogenation of cyclooctane.
ファイル公開:2019-04-23
ACS Publications
2018-04-23
eng
journal article
AM
http://hdl.handle.net/2237/00028458
https://nagoya.repo.nii.ac.jp/records/26254
https://doi.org/10.1021/acs.organomet.8b00072
0276-7333
Organometallics
37
8
1304
1313
https://nagoya.repo.nii.ac.jp/record/26254/files/20180404_Text.pdf
application/pdf
1.2 MB
2019-04-23