2024-03-29T15:39:38Z
https://nagoya.repo.nii.ac.jp/oai
oai:nagoya.repo.nii.ac.jp:00027960
2023-01-16T05:03:44Z
1903:1904:1905
Synthesis of the [7-5-5] tricyclic core of Daphniphyllum alkaloids
Kitabayashi, Yusuke
Fukuyama, Tohru
Yokoshima, Satoshi
open access
The [7-5-5] tricyclic core of the Daphniphyllum alkaloids was constructed, featuring a Claisen-Ireland rearrangement to install the two contiguous stereogenic centers, E1cB elimination to form the tetrasubstituted C–C double bond, and a 2,3-Wittig rearrangement to construct the quaternary carbon. Ring-closing metathesis and an intramolecular carbonyl ene reaction were employed for construction of the requisite ring system.
ファイル公開:2019/05/21
Royal Society of Chemistry
2018-05-21
eng
journal article
AM
http://hdl.handle.net/2237/00030158
https://nagoya.repo.nii.ac.jp/records/27960
https://doi.org/10.1039/C8OB00859K
1477-0520
Organic & Biomolecular Chemistry
16
19
3556
3559
https://nagoya.repo.nii.ac.jp/record/27960/files/20180412.pdf
application/pdf
615.3 kB
2019-05-21