2024-03-29T02:03:49Z
https://nagoya.repo.nii.ac.jp/oai
oai:nagoya.repo.nii.ac.jp:00030139
2023-01-16T05:03:46Z
1903:1904:1905
Synthetic Studies on Bilobalide
Shiogai, Akihiro
Toma, Tatsuya
Yokoshima, Satoshi
open access
desymmetrization
Diels–Alder reaction
Mukaiyama hydration
quaternary carbon
tertiary alcohol
We disclose our synthetic studies on bilobalide, which features a Diels–Alder reaction of a cyclic anhydride to form two contiguous quaternary carbon centers, desymmetrization of a symmetric diol, and construction of a cyclic acetal under acidic conditions with inversion of configuration at an allylic position.
ファイル公開:2021-02-01
Georg Thieme Verlag
2020-02
eng
journal article
AM
http://hdl.handle.net/2237/00032325
https://nagoya.repo.nii.ac.jp/records/30139
https://doi.org/10.1055/s-0039-1691559
0936-5214
Synlett
31
03
290
294
https://nagoya.repo.nii.ac.jp/record/30139/files/20191125_shiogai_rev.pdf
application/pdf
370.7 kB
2021-02-01