2024-03-28T10:32:06Z
https://nagoya.repo.nii.ac.jp/oai
oai:nagoya.repo.nii.ac.jp:02001484
2023-01-16T05:15:53Z
336:695:696
Variable Host–Guest Charge-Transfer Interactions in 1D Channels Formed in a Molecule-Based Honeycomb Lattice of Phenazine Analogue of Triptycene
Ushiroguchi, Ryo
Shuku, Yoshiaki
Suizu, Rie
Awaga, Kunio
open access
“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Crystal Growth & Design], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-4CMTEDVRQFQ8IIZSSMS2].”
We synthesized a phenazine analogue of triptycene acceptor, Trip-Phz, and found a honeycomb network of Trip-Phz with a wide 1D channel running through it. The interior surface of this channel was covered by the π electrons of Trip-Phz. Even though there was no interaction between Trip-Phz and an organic donor, tetrathiafulvalene (TTF), in their solutions, the honeycomb crystals of Trip-Phz exhibited a host–guest charge-transfer (CT) interaction with TTF, specifically a reversible adsorption/desorption of TTF with the appearance/disappearance of a CT band.
ACS Publications
2021-12-02
2020-12-02
eng
journal article
AM
http://hdl.handle.net/2237/0002001484
https://nagoya.repo.nii.ac.jp/records/2001484
https://doi.org/10.1021/acs.cgd.0c01176
1528-7483
Crystal Growth & Design
20
12
7593
7597
https://nagoya.repo.nii.ac.jp/record/2001484/files/revised3_text.pdf
application/pdf
7.9 MB
2021-12-02