2024-03-28T18:44:58Z
https://nagoya.repo.nii.ac.jp/oai
oai:nagoya.repo.nii.ac.jp:00010388
2023-01-16T03:56:08Z
367:368:369:1144
Relative REE abundances of porewater in Pacific pelagic sediment: estimation by equilibrium calculations based on REE composition of Mn-oxide and apatite components
TAKEBE, Masamichi
31590
YAMAMOTO, Koshi
31591
REE composition
Porewater
Pelagic sediment
Equilibrium calculation
2007-12-25
In order to reveal REE mobilization in sediment during early diagenesis, we estimate the REE composition of porewater in Pacific sediments deposited in the Equatorial area. The Pacific sediment was divided chemically into leachate 1 (extracted by alkaline Na_2S_2O_4), leachate 2 (extracted by 0.17 M HCl) and residue. The leachate 1, leachate 2 and residue consist mainly of Mn oxide, carbonate fluorapatite (CFA), and detrital materials, respectively. The Mn oxide and CFA component are considered to provide information about REE composition of porewater. Assuming that Mn oxide and CFA in the sediment were in chemical equilibrium with the porewater in terms of REE, the REE composition (REE/Gd ratio) of the porewater in the sediment was estimated from the REE abundance of the leachate 1 and 2. The estimated REE pattern (REE/Gd ratio) of the porewater shows La depletion and Ce enrichment relative to the deep-seawater. The difference of REE composition between deep-seawater and porewater suggests that REE in pelagic sediment is mobilized during early diagenesis.
departmental bulletin paper
名古屋大学博物館
2007-12-25
名古屋大学博物館報告
23
1
12
http://hdl.handle.net/2237/12208
13468286
eng