2024-03-28T15:55:42Z
https://nagoya.repo.nii.ac.jp/oai
oai:nagoya.repo.nii.ac.jp:00024035
2023-01-16T04:14:13Z
336:695:696
Location of Methanol on the S2 State Mn Cluster in Photosystem II Studied by Proton Matrix Electron Nuclear Double Resonance
Nagashima, Hiroki
71349
Mino, Hiroyuki
71350
Proton matrix electron nuclear double resonance (ENDOR) spectroscopy was performed to specify the location of the methanol molecule near the manganese cluster in photosystem II. Comparison of the ENDOR spectra in the presence of CH3OH and CD3OH revealed two pairs of hyperfine couplings, 1.2 MHz for A⊥ and 2.5 MHz for A//, arising from the methyl group in methanol. On the basis of the crystal structure, the possible location of methanol close to the manganese cluster was discussed.
journal article
ACS Publications
2017-01-18
application/pdf
The Journal of Physical Chemistry Letters
3
8
621
625
http://doi.org/10.1021/acs.jpclett.7b00110
http://hdl.handle.net/2237/26251
1948-7185
https://nagoya.repo.nii.ac.jp/record/24035/files/manuscript_finalforlibrary.pdf
eng
https://doi.org/10.1021/acs.jpclett.7b00110
“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [The Journal of Physical Chemistry Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-fiyDvy4ndtabRfsuCBiv].”