2024-03-28T19:02:00Z
https://nagoya.repo.nii.ac.jp/oai
oai:nagoya.repo.nii.ac.jp:00024038
2023-01-16T05:03:43Z
1903:1904:1905
Ruthenium-Catalyzed Cycloisomerization of 1,6-Diynes with Styryl Terminals Leading to Indenylidene Cycloalkanes
Yamamoto, Yoshihiko
71355
Nishimura, Kei-ichiro
71356
Shibuya, Masatoshi
71357
cycloisomerization
enediyne
indenylidenecycloalkane
ruthenium catalyst
spirocycle
In the presence of a neutral ruthenium catalyst, Cp*RuCl(cod), 1,5,10-enediynes bearing a styryl terminal underwent cycloisomerization to afford exocyclic 1,3-dienes with an indenylidene moiety. The reaction mechanism is proposed on the basis of the results of control experiments and density functional calculations. The transformations of the obtained cyclization products were also investigated to demonstrate the synthetic potential of this method.
journal article
ACS Publications
2016-12-22
application/pdf
ACS Catalysis
2
7
1101
1107
http://doi.org/10.1021/acscatal.6b03322
http://hdl.handle.net/2237/26253
2155-5435
https://nagoya.repo.nii.ac.jp/record/24038/files/ACS_Cat_MS_RevMarked.pdf
eng
https://doi.org/10.1021/acscatal.6b03322
“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Catalysis], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-aitDP7XGZQ7EvxB3zTx3].”