2024-03-28T15:48:43Z
https://nagoya.repo.nii.ac.jp/oai
oai:nagoya.repo.nii.ac.jp:00026596
2023-01-16T04:29:14Z
1935:1936:1937
Synthesis of an All-Ferric Cuboidal Iron-Sulfur Cluster [Fe^III4S4(SAr)4]
Moula, Golam
87949
Matsumoto, Tsuyoshi
87950
Miehlich, Matthias E.
87951
Meyer, Karsten
87952
Tatsumi, Kazuyuki
87953
high oxidation states
iron–sulfur cubane cluster
magnetism
Mössbauer spectroscopy
An unprecedented, super oxidized all‐ferric iron–sulfur cubanoid cluster with all terminal thiolates, Fe4S4(STbt)4 (3) [Tbt=2,4,6‐tris{bis(trimethylsilyl)methyl}phenyl], has been isolated from the reaction of the bis‐thiolate complex Fe(STbt)2 (2) with elemental sulfur. This cluster 3 has been characterized by X‐ray crystallography, zero‐field 57Fe Mössbauer spectroscopy, cyclic voltammetry, and other relevant physico‐chemical methods. Based on all the data, the electronic ground state of the cluster has been assigned to be Stot=0.
ファイル公開:2019/09/03
journal article
Wiley
2018-09-03
application/pdf
Angewandte Chemie International Edition
36
57
11594
11597
1433-7851
1521-3773
https://nagoya.repo.nii.ac.jp/record/26596/files/anie201803679.pdf
eng
https://doi.org/10.1002/anie.201803679
This is the peer reviewed version of the following article: [G. Moula, T. Matsumoto, M. E. Miehlich, K. Meyer, K. Tatsumi, Angew. Chem. Int. Ed. 2018, 57, 11594.], which has been published in final form at [https://doi.org/10.1002/anie.201803679]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.