2024-03-29T09:09:39Z
https://nagoya.repo.nii.ac.jp/oai
oai:nagoya.repo.nii.ac.jp:02001416
2023-01-16T05:14:45Z
320:321:322
Site-selective halogenation on meso-mesityl substituents of 10,20-dimesityl-5,15-diazaporphyrins with an AuX3/AgOTf combination
Longevial, Jean-François
Miyagawa, Kazuya
Shinokubo, Hiroshi
We have developed site-selective bromination on the mesityl substituents of 10,20-dimesityl-5,15-diazaporphyrins. Treatment of 10,20-dimesityl-5,15-diazaporphyrin and its nickel(II) complex with a combination of AuBr3/AgOTf induced selective bromination on the mesityl groups. These brominated products can be employed for late-stage modification of the aryl substituents.
journal article
Royal Society of Chemistry
2020-11-14
application/pdf
Dalton Transactions
42
49
14786
14789
1477-9226
https://nagoya.repo.nii.ac.jp/record/2001416/files/Jeff-0919_reviseed.pdf
eng
https://doi.org/10.1039/D0DT02727H