{"created":"2021-03-01T06:17:19.255929+00:00","id":10490,"links":{},"metadata":{"_buckets":{"deposit":"8236b6be-3a5e-4b8e-90a4-6bd0eb846788"},"_deposit":{"id":"10490","owners":[],"pid":{"revision_id":0,"type":"depid","value":"10490"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00010490","sets":["320:321:322"]},"author_link":["31801","31802","31803"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2008-03-24","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"13","bibliographicPageEnd":"2172","bibliographicPageStart":"2170","bibliographicVolumeNumber":"49","bibliographic_titles":[{"bibliographic_title":"Tetrahedron Letters","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Direct functionalization of aromatic substituents on [28]hexaphyrin was achieved by iridium-catalyzed borylation with theSmith–Miyaura–Hartwig protocol. High para selectivity was observed in the reaction on 2,6-dichlorophenyl and 2,6-dimethoxyphenylsubstituents of [28]hexaphyrin. The reaction with [26]hexaphyrin resulted only in reduction of the substrate to provide [28]hexaphyrinwithout borylation, thus highlighting the importance of the oxidation state of substrates in this catalytic transformation. The borylatedhexaphyrin can be used for Suzuki–Miyaura cross coupling reaction.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/12313"},{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://dx.doi.org/10.1016/j.tetlet.2008.01.069"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.tetlet.2008.01.069","subitem_relation_type_select":"DOI"}}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0040-4039","subitem_source_identifier_type":"PISSN"}]},"item_10_text_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_text_value":"application/pdf"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Mori, Goro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"31801","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shinokubo, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"31802","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Osuka, Atsuhiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"31803","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-02-20"}],"displaytype":"detail","filename":"Dmori0109.pdf","filesize":[{"value":"74.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Dmori0109.pdf","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/10490/files/Dmori0109.pdf"},"version_id":"ddbb7ad4-2063-47e5-9716-f7693612c10f"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Highly selective Ir-catalyzed direct sixfold borylation of peripheral aromatic substituents on hexakisaryl-substituted [28]hexaphyrin(1.1.1.1.1.1)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Highly selective Ir-catalyzed direct sixfold borylation of peripheral aromatic substituents on hexakisaryl-substituted [28]hexaphyrin(1.1.1.1.1.1)","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2009-11-02"},"publish_date":"2009-11-02","publish_status":"0","recid":"10490","relation_version_is_last":true,"title":["Highly selective Ir-catalyzed direct sixfold borylation of peripheral aromatic substituents on hexakisaryl-substituted [28]hexaphyrin(1.1.1.1.1.1)"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T03:56:25.112516+00:00"}