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A theoretical study on the frequency-dependent electric conductivity of electrolyte solutions. II. Effect of hydrodynamic interaction
http://hdl.handle.net/2237/12627
http://hdl.handle.net/2237/1262774257f67-5bb1-4664-9f86-cad2e7094843
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2010-01-20 | |||||
タイトル | ||||||
タイトル | A theoretical study on the frequency-dependent electric conductivity of electrolyte solutions. II. Effect of hydrodynamic interaction | |||||
言語 | en | |||||
著者 |
Yamaguchi, T
× Yamaguchi, T× Matsuoka, T× Koda, S |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | Copyright (2009) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior per mission of the author and the American Institute of Physics. | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | electrical conductivity | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | electrolytes | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | hydrodynamics | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | sodium compounds | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | solutions | |||||
抄録 | ||||||
内容記述 | The theory on the frequency-dependent electric conductivity of electrolyte solutions proposedpreviously by Yamaguchi et al. [J. Chem. Phys. 127, 234501 (2007)] is extended to include thehydrodynamic interaction between ions. The theory is applied to the aqueous solution of NaCl andthe concentration dependence of the conductivity agrees well with that determined by experiments.The effects of the hydrodynamic and relaxation effects are highly nonadditive in the concentratedsolution, because the hydrodynamic interaction between ions affects the time-dependent response of the ionic atmosphere. The decrease in the electric conductivity is divided into the contributions of ion pair distribution at various distances. The long-range ionic atmosphere plays a major role at the concentration as low as 0.01 mol/kg, whereas the contribution of the contact ion pair region is important at 1 mol/kg. The magnitude of the contribution of the contact ion pair region is scarcely dependent on the presence of the hydrodynamic interaction. The transport number of cation is calculated to be a decreasing function of concentration as is observed in experiments. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | American Institite of Physics | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1063/1.3085717 | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 0021-9606 | |||||
書誌情報 |
en : THE JOURNAL OF CHEMICAL PHYSICS 巻 130, 号 9, p. 094506-094506, 発行日 2009-03-06 |
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フォーマット | ||||||
application/pdf | ||||||
著者版フラグ | ||||||
値 | publisher | |||||
URI | ||||||
識別子 | http://hdl.handle.net/2237/12627 | |||||
識別子タイプ | HDL | |||||
URI | ||||||
識別子 | http://dx.doi.org/10.1063/1.3085717 | |||||
識別子タイプ | DOI |