{"created":"2021-03-01T06:17:38.293507+00:00","id":10787,"links":{},"metadata":{"_buckets":{"deposit":"d45f47c6-d7ab-4e34-8954-958550bdb809"},"_deposit":{"id":"10787","owners":[],"pid":{"revision_id":0,"type":"depid","value":"10787"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00010787","sets":["336:695:696"]},"author_link":["32402"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009-04-16","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"15","bibliographicPageEnd":"154103","bibliographicPageStart":"154103","bibliographicVolumeNumber":"130","bibliographic_titles":[{"bibliographic_title":"THE JOURNAL OF CHEMICAL PHYSICS","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"General theory of the excitation energy transfer (EET) in the case of donor-mediator-acceptor system was constructed by using generalized master equation (GME). In this theory, we consider the direct and indirect transitions in the EET consistently. Hence, our theory includes the quantum mechanical interference between the direct and indirect transitions automatically. Memory functions in the GME were expressed by the overlap integrals among the time-dependent emission spectrum of the donor, the absorption spectrum of the mediator, the time-dependent emission spectrum of the mediator, and the absorption spectrum of the acceptor. In the Markov limit of the memory functions, we obtained the rate of EET which consists of three terms due to the direct transition, the indirect transition, and the interference between them. We found that the interference works effectively in the limit of slow thermalization at the intermediate state. The formula of EET rate in this limit was expressed by the convolution of the EET interaction and optical spectra. The interference effect strongly depends on the width of the absorption spectrum of mediator molecule and the energy gap between the donor and the mediator molecules.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/12630"},{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://dx.doi.org/10.1063/1.3117622"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"American Institite of Physics","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1063/1.3117622","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright (2009) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior per　mission of the author and the American Institute of Physics.","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0021-9606","subitem_source_identifier_type":"PISSN"}]},"item_10_text_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_text_value":"application/pdf"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kimura, Akihiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"32402","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-02-20"}],"displaytype":"detail","filename":"JChemPhys_130_154103.pdf","filesize":[{"value":"361.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"JChemPhys_130_154103.pdf","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/10787/files/JChemPhys_130_154103.pdf"},"version_id":"e359f655-5250-4b9c-880f-85add7064e3a"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"excited states","subitem_subject_scheme":"Other"},{"subitem_subject":"luminescence","subitem_subject_scheme":"Other"},{"subitem_subject":"Markov processes","subitem_subject_scheme":"Other"},{"subitem_subject":"master equation","subitem_subject_scheme":"Other"},{"subitem_subject":"molecular electronic states","subitem_subject_scheme":"Other"},{"subitem_subject":"transition moments","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"General theory of excitation energy transfer in donor-mediator-acceptor systems","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"General theory of excitation energy transfer in donor-mediator-acceptor systems","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["696"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2010-01-21"},"publish_date":"2010-01-21","publish_status":"0","recid":"10787","relation_version_is_last":true,"title":["General theory of excitation energy transfer in donor-mediator-acceptor systems"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T03:56:42.190263+00:00"}