{"_buckets": {"deposit": "5f144000-0a17-4e24-8c1f-439228804162"}, "_deposit": {"created_by": 17, "id": "2001391", "owner": "17", "owners": [17], "owners_ext": {"displayname": "図書情報係", "username": "repository"}, "pid": {"revision_id": 0, "type": "depid", "value": "2001391"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:02001391", "sets": ["322"]}, "author_link": [], "control_number": "2001391", "item_1615768549627": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_1629683748249": {"attribute_name": "日付", "attribute_value_mlt": [{"subitem_date_issued_datetime": "2022-02-01", "subitem_date_issued_type": "Available"}]}, "item_9_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2021-02", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "2", "bibliographicPageEnd": "365", "bibliographicPageStart": "360", "bibliographicVolumeNumber": "10", "bibliographic_titles": [{"bibliographic_title": "Asian Journal of Organic Chemistry", "bibliographic_titleLang": "en"}]}]}, "item_9_description_4": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "Silica-supported ammonium (R)-BINSate catalysts for the enantio- and diastereoselective Friedel–Crafts-type double aminoalkylation of N-benzyl- or N-methylpyrrole with aldimines were developed. The present heterogeneous catalysts showed high catalytic activity compared to our previous homogeneous (R)-BINSA ammonium catalysts, which were effective for single aminoalkylation. Simple aldimines could be used, and the corresponding pyrrole-derived chiral C2-symmetric triamines were obtained in the dl-form with good to extremely high enantioselectivities. The heterogeneous catalyst could be easily recovered and reused three times without any loss of catalytic activity or enantiocontrol. An XPS analysis supported precise preparation of the catalysts in situ and with good quality after recycling three times. From the perspective of modern green chemistry with fine asymmetric organocatalysis, the development of such chiral strong Brønsted acid catalysts might be useful for both laboratory and industrial applications.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_9_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Wiley", "subitem_publisher_language": "en"}]}, "item_9_relation_43": {"attribute_name": "関連情報", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/ajoc.202000603", "subitem_relation_type_select": "DOI"}}]}, "item_9_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [M. Hatano, X. Zhao, T. Mochizuki, K. Maeda, K. Motokura, K. Ishihara, Asian J. Org. Chem. 2021, 10, 360.], which has been published in final form at [https://doi.org/10.1002/ajoc.202000603]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.\"", "subitem_rights_language": "en"}]}, "item_9_source_id_7": {"attribute_name": "収録物識別子", "attribute_value_mlt": [{"subitem_source_identifier": "2193-5815", "subitem_source_identifier_type": "EISSN"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Hatano, Manabu", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Zhao, Xue", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Mochizuki, Takuya", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Maeda, Kyogo", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Motokura, Ken", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Ishihara, Kazuaki", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2022-02-01"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Hatano.pdf", "filesize": [{"value": "816 KB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "mimetype": "application/pdf", "size": 816000.0, "url": {"objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/2001391/files/Hatano.pdf"}, "version_id": "56977b30-7df6-40ad-8ee3-c0f507fe7725"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Reusable Silica-Supported Ammonium BINSate Catalysts for Enantio- and Diastereoselective Friedel–Crafts-Type Double Aminoalkylation of N-Alkylpyrroles with Aldimines", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Reusable Silica-Supported Ammonium BINSate Catalysts for Enantio- and Diastereoselective Friedel–Crafts-Type Double Aminoalkylation of N-Alkylpyrroles with Aldimines", "subitem_title_language": "en"}]}, "item_type_id": "40001", "owner": "17", "path": ["322"], "permalink_uri": "http://hdl.handle.net/2237/0002001391", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2021-09-08"}, "publish_date": "2021-09-08", "publish_status": "0", "recid": "2001391", "relation": {}, "relation_version_is_last": true, "title": ["Reusable Silica-Supported Ammonium BINSate Catalysts for Enantio- and Diastereoselective Friedel–Crafts-Type Double Aminoalkylation of N-Alkylpyrroles with Aldimines"], "weko_shared_id": -1}