{"_buckets": {"deposit": "a0557f49-9af5-41d2-9df9-aaaf43f2fd56"}, "_deposit": {"created_by": 17, "id": "2001419", "owner": "17", "owners": [17], "owners_ext": {"displayname": "\u56f3\u66f8\u60c5\u5831\u4fc2", "username": "repository"}, "pid": {"revision_id": 0, "type": "depid", "value": "2001419"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:02001419", "sets": []}, "author_link": [], "control_number": "2001419", "item_1615768549627": {"attribute_name": "\u51fa\u7248\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_1629683748249": {"attribute_name": "\u65e5\u4ed8", "attribute_value_mlt": [{"subitem_date_issued_datetime": "2021-12-31", "subitem_date_issued_type": "Available"}]}, "item_9_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-12-31", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "48", "bibliographicPageEnd": "7465", "bibliographicPageStart": "7455", "bibliographicVolumeNumber": "2020", "bibliographic_titles": [{"bibliographic_title": "European Journal of Organic Chemistry", "bibliographic_titleLang": "en"}]}]}, "item_9_description_4": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "The mechanisms of the palladium(0)-catalyzed cross [2+2+2] cycloaddition of a diyne diester with dimethyl acetylenedicarboxylate and of the [2+2+2] cyclization of a triyne diester were investigated using density functional theory calculations. After evaluating the kinetic and thermodynamic profiles of each reaction, the roles of the ester substituents on the alkyne substrates and of the triphenylphosphine ligand are discussed based on the obtained results. Moreover, the previously unreported cross [2+2+2] cycloaddition of the diyne diester with nitriles was also investigated, in order to evaluate its feasibility under the relevant experimental conditions.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_9_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley", "subitem_publisher_language": "en"}]}, "item_9_relation_43": {"attribute_name": "\u95a2\u9023\u60c5\u5831", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/ejoc.202001349", "subitem_relation_type_select": "DOI"}}]}, "item_9_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [Yamamoto, Y. (2020), Theoretical Study of the Mechanism of Palladium(0)-Catalyzed Intramolecular [2+2+2] Cycloaddition of Ester-Substituted Alkynes. Eur. J. Org. Chem., 2020: 7455-7465. https://doi.org/10.1002/ejoc.202001349], which has been published in final form at [https://doi.org/10.1002/ejoc.202001349]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley\u2019s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.\"", "subitem_rights_language": "en"}]}, "item_9_source_id_7": {"attribute_name": "\u53ce\u9332\u7269\u8b58\u5225\u5b50", "attribute_value_mlt": [{"subitem_source_identifier": "1434-193X", "subitem_source_identifier_type": "PISSN"}]}, "item_access_right": {"attribute_name": "\u30a2\u30af\u30bb\u30b9\u6a29", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Yamamoto, Yoshihiko", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2021-12-31"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "manuscript.pdf", "filesize": [{"value": "4.1 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "mimetype": "application/pdf", "size": 4099999.9999999995, "url": {"objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/2001419/files/manuscript.pdf"}, "version_id": "c176c994-1a90-4dc3-a51f-809a6bf11538"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Theoretical Study of the Mechanism of Palladium(0)\u2010Catalyzed Intramolecular [2+2+2] Cycloaddition of Ester\u2010Substituted Alkynes", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Theoretical Study of the Mechanism of Palladium(0)\u2010Catalyzed Intramolecular [2+2+2] Cycloaddition of Ester\u2010Substituted Alkynes", "subitem_title_language": "en"}]}, "item_type_id": "40001", "owner": "17", "path": ["1903/1904/1905"], "permalink_uri": "http://hdl.handle.net/2237/0002001419", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2021-09-10"}, "publish_date": "2021-09-10", "publish_status": "0", "recid": "2001419", "relation": {}, "relation_version_is_last": true, "title": ["Theoretical Study of the Mechanism of Palladium(0)\u2010Catalyzed Intramolecular [2+2+2] Cycloaddition of Ester\u2010Substituted Alkynes"], "weko_shared_id": -1}