ログイン
言語:

WEKO3

  • トップ
  • ランキング
To
lat lon distance
To

Field does not validate



インデックスリンク

インデックスツリー

メールアドレスを入力してください。

WEKO

One fine body…

WEKO

One fine body…

アイテム

{"_buckets": {"deposit": "a0557f49-9af5-41d2-9df9-aaaf43f2fd56"}, "_deposit": {"created_by": 17, "id": "2001419", "owner": "17", "owners": [17], "owners_ext": {"displayname": "図書情報係", "username": "repository"}, "pid": {"revision_id": 0, "type": "depid", "value": "2001419"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:02001419", "sets": ["1905"]}, "author_link": [], "control_number": "2001419", "item_1615768549627": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_1629683748249": {"attribute_name": "日付", "attribute_value_mlt": [{"subitem_date_issued_datetime": "2021-12-31", "subitem_date_issued_type": "Available"}]}, "item_9_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-12-31", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "48", "bibliographicPageEnd": "7465", "bibliographicPageStart": "7455", "bibliographicVolumeNumber": "2020", "bibliographic_titles": [{"bibliographic_title": "European Journal of Organic Chemistry", "bibliographic_titleLang": "en"}]}]}, "item_9_description_4": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "The mechanisms of the palladium(0)-catalyzed cross [2+2+2] cycloaddition of a diyne diester with dimethyl acetylenedicarboxylate and of the [2+2+2] cyclization of a triyne diester were investigated using density functional theory calculations. After evaluating the kinetic and thermodynamic profiles of each reaction, the roles of the ester substituents on the alkyne substrates and of the triphenylphosphine ligand are discussed based on the obtained results. Moreover, the previously unreported cross [2+2+2] cycloaddition of the diyne diester with nitriles was also investigated, in order to evaluate its feasibility under the relevant experimental conditions.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_9_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Wiley", "subitem_publisher_language": "en"}]}, "item_9_relation_43": {"attribute_name": "関連情報", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/ejoc.202001349", "subitem_relation_type_select": "DOI"}}]}, "item_9_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [Yamamoto, Y. (2020), Theoretical Study of the Mechanism of Palladium(0)-Catalyzed Intramolecular [2+2+2] Cycloaddition of Ester-Substituted Alkynes. Eur. J. Org. Chem., 2020: 7455-7465. https://doi.org/10.1002/ejoc.202001349], which has been published in final form at [https://doi.org/10.1002/ejoc.202001349]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.\"", "subitem_rights_language": "en"}]}, "item_9_source_id_7": {"attribute_name": "収録物識別子", "attribute_value_mlt": [{"subitem_source_identifier": "1434-193X", "subitem_source_identifier_type": "PISSN"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Yamamoto, Yoshihiko", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2021-12-31"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "manuscript.pdf", "filesize": [{"value": "4.1 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "mimetype": "application/pdf", "size": 4099999.9999999995, "url": {"objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/2001419/files/manuscript.pdf"}, "version_id": "c176c994-1a90-4dc3-a51f-809a6bf11538"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Theoretical Study of the Mechanism of Palladium(0)‐Catalyzed Intramolecular [2+2+2] Cycloaddition of Ester‐Substituted Alkynes", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Theoretical Study of the Mechanism of Palladium(0)‐Catalyzed Intramolecular [2+2+2] Cycloaddition of Ester‐Substituted Alkynes", "subitem_title_language": "en"}]}, "item_type_id": "40001", "owner": "17", "path": ["1905"], "permalink_uri": "http://hdl.handle.net/2237/0002001419", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2021-09-10"}, "publish_date": "2021-09-10", "publish_status": "0", "recid": "2001419", "relation": {}, "relation_version_is_last": true, "title": ["Theoretical Study of the Mechanism of Palladium(0)‐Catalyzed Intramolecular [2+2+2] Cycloaddition of Ester‐Substituted Alkynes"], "weko_shared_id": -1}
  1. D400 創薬科学研究科
  2. D400a 雑誌掲載論文
  3. 学術雑誌

Theoretical Study of the Mechanism of Palladium(0)‐Catalyzed Intramolecular [2+2+2] Cycloaddition of Ester‐Substituted Alkynes

http://hdl.handle.net/2237/0002001419
http://hdl.handle.net/2237/0002001419
ba65259c-d3c1-4d3f-bdaf-ce10054d99e7
名前 / ファイル ライセンス アクション
manuscript.pdf manuscript.pdf (4.1 MB)
Item type itemtype_ver1(1)
公開日 2021-09-10
タイトル
タイトル Theoretical Study of the Mechanism of Palladium(0)‐Catalyzed Intramolecular [2+2+2] Cycloaddition of Ester‐Substituted Alkynes
言語 en
著者 Yamamoto, Yoshihiko

× Yamamoto, Yoshihiko

en Yamamoto, Yoshihiko

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 "This is the peer reviewed version of the following article: [Yamamoto, Y. (2020), Theoretical Study of the Mechanism of Palladium(0)-Catalyzed Intramolecular [2+2+2] Cycloaddition of Ester-Substituted Alkynes. Eur. J. Org. Chem., 2020: 7455-7465. https://doi.org/10.1002/ejoc.202001349], which has been published in final form at [https://doi.org/10.1002/ejoc.202001349]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited."
内容記述
内容記述 The mechanisms of the palladium(0)-catalyzed cross [2+2+2] cycloaddition of a diyne diester with dimethyl acetylenedicarboxylate and of the [2+2+2] cyclization of a triyne diester were investigated using density functional theory calculations. After evaluating the kinetic and thermodynamic profiles of each reaction, the roles of the ester substituents on the alkyne substrates and of the triphenylphosphine ligand are discussed based on the obtained results. Moreover, the previously unreported cross [2+2+2] cycloaddition of the diyne diester with nitriles was also investigated, in order to evaluate its feasibility under the relevant experimental conditions.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
関連情報
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/ejoc.202001349
収録物識別子
収録物識別子タイプ PISSN
収録物識別子 1434-193X
書誌情報 en : European Journal of Organic Chemistry

巻 2020, 号 48, p. 7455-7465, 発行日 2020-12-31
ファイル公開日
日付 2021-12-31
日付タイプ Available
戻る
0
views
See details
Views

Versions

Ver.1 2021-09-10 01:57:07.302457
Show All versions

Share

Mendeley Twitter Facebook Print Addthis

Cite as

エクスポート

OAI-PMH
  • OAI-PMH JPCOAR
  • OAI-PMH DublinCore
  • OAI-PMH DDI
Other Formats
  • JSON
  • BIBTEX

Confirm


Powered by WEKO3


Powered by WEKO3