@article{oai:nagoya.repo.nii.ac.jp:02001506,
 author = {Jin, Yuan and Orihara, Kensuke and Kawagishi, Fumiki and Toma, Tatsuya and Fukuyama, Tohru and Yokoshima, Satoshi},
 issue = {17},
 journal = {Angewandte Chemie International Edition},
 month = {Apr},
 note = {The total synthesis of haliclonin A was accomplished. Starting from 3,5-dimethoxybenzoic acid, a functionalized cyclohexanone fused to a 17-membered ring was prepared through a Birch reduction/alkylation sequence, ring-closing metathesis, intramolecular cyclopropanation, and stereoselective 1,4-addition of an organocopper reagent to an enone moiety. Reductive C−N bond formation via an N,O-acetal forged the 3-azabicyclo[3.3.1]nonane core. The allyl alcohol moiety was constructed by a sequence involving stereoselective α-selenylation of an aldehyde via an enamine, syn-elimination of a selenoxide, and allylation of the aldehyde with an allylboronate. Formation of the 15-membered ring containing a skipped diene was achieved by ring-closing metathesis, and final transformations led to the synthesis of haliclonin A.},
 pages = {9666--9671},
 title = {Total Synthesis of Haliclonin A},
 volume = {60},
 year = {2021}
}