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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Chemoselective Transesterification of Methyl (Meth)acrylates Catalyzed by Sodium(I) or Magnesium(II) Aryloxides

http://hdl.handle.net/2237/0002001529
http://hdl.handle.net/2237/0002001529
7a0de3af-425e-41eb-b6b1-b4d31441f89b
名前 / ファイル ライセンス アクション
ACS_Catal_2021_11_199.pdf ACS_Catal_2021_11_199.pdf (2.1 MB)
Item type itemtype_ver1(1)
公開日 2021-10-18
タイトル
タイトル Chemoselective Transesterification of Methyl (Meth)acrylates Catalyzed by Sodium(I) or Magnesium(II) Aryloxides
言語 en
著者 Ng, Jie Qi

× Ng, Jie Qi

en Ng, Jie Qi

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Arima, Hiro

× Arima, Hiro

en Arima, Hiro

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Mochizuki, Takuya

× Mochizuki, Takuya

en Mochizuki, Takuya

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Toh, Kohei

× Toh, Kohei

en Toh, Kohei

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Matsui, Kai

× Matsui, Kai

en Matsui, Kai

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Ratanasak, Manussada

× Ratanasak, Manussada

en Ratanasak, Manussada

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Hasegawa, Jun-Ya

× Hasegawa, Jun-Ya

en Hasegawa, Jun-Ya

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Hatano, Manabu

× Hatano, Manabu

en Hatano, Manabu

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Ishihara, Kazuaki

× Ishihara, Kazuaki

en Ishihara, Kazuaki

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アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 "This document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Catalysis], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-7KX9BNCFYYVVFQZEDJ89].”
内容記述
内容記述 A highly chemoselective transesterification of methyl (meth)acrylates catalyzed by sterically demanding 2,6-di-tert-butyl-4-methylphenol-derived NaOAr or Mg(OAr)2 was developed. The desired transesterification proceeded without the undesired Michael additions under mild reaction conditions at 25 °C, and various primary and secondary alcohols, diols, triol, and tetraol on a scale of up to 10 mmol could provide the corresponding functionalized acrylates in high yields. Transition states were proposed based on monomeric and dimeric active species, and computational density functional theory calculations strongly supported high chemoselectivity to minimize undesired Michael additions.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 ACS Publications
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
関連情報
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1021/acscatal.0c04217
収録物識別子
収録物識別子タイプ EISSN
収録物識別子 2155-5435
書誌情報 en : ACS Catalysis

巻 11, 号 1, p. 199-207, 発行日 2021-01-01
ファイル公開日
日付 2022-01-01
日付タイプ Available
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