{"_buckets": {"deposit": "15a56abd-d7c3-49d6-b959-ad7cd24c5c77"}, "_deposit": {"created_by": 17, "id": "2001679", "owner": "17", "owners": [17], "owners_ext": {"displayname": "\u56f3\u66f8\u60c5\u5831\u4fc2", "username": "repository"}, "pid": {"revision_id": 0, "type": "depid", "value": "2001679"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:02001679"}, "author_link": [], "item_1615768549627": {"attribute_name": "\u51fa\u7248\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_1629683748249": {"attribute_name": "\u65e5\u4ed8", "attribute_value_mlt": [{"subitem_date_issued_datetime": "2022-05-28", "subitem_date_issued_type": "Available"}]}, "item_9_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2021-05-28", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "5", "bibliographicPageEnd": "4541", "bibliographicPageStart": "4532", "bibliographicVolumeNumber": "4", "bibliographic_titles": [{"bibliographic_title": "ACS Applied Nano Materials", "bibliographic_titleLang": "en"}]}]}, "item_9_description_4": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "The structure\u2013catalytic property relationships of Al2O3-supported Pt\u2013Sn nanoparticles (Pt\u2013Sn/Al2O3) in the dehydrogenation of methylcyclohexane (MCH) were investigated by varying the Sn/Pt ratios of the catalysts. The initial activity and the deactivation rate of the Pt\u2013Sn/Al2O3 catalysts in the MCH dehydrogenation decreased in line with an increase in the Sn/Pt ratio from 0 to 3. The Pt\u2013Sn/Al2O3 catalyst with a Sn/Pt ratio of 2 showed good activity, durability, and toluene selectivity in the MCH dehydrogenation among the series of catalysts. The dispersion of Pt in the Pt\u2013Sn/Al2O3 catalysts was observed to decrease with an increase in the Sn/Pt ratio. Structural changes in the catalysts from Pt\u2013Sn clusters to intermetallic Pt3Sn and PtSn nanoparticles were also observed using scanning transmission electron microscopy and X-ray diffraction. According to structural analysis using X-ray absorption fine-structure spectroscopy and infrared spectroscopy using carbon monoxide as a probe, the electron density of Pt increased, and the fraction of Pt\u2013Pt adjacent sites decreased with an increase in the Sn/Pt ratio. Comparing the catalytic properties and the structures of the Pt\u2013Sn/Al2O3 catalysts, their initial activities were correlated with the dispersion of Pt. In addition, the durability and selectivity of the catalysts were enhanced due to an increase in the electron density of Pt and a decrease in the number of Pt\u2013Pt adjacent sites. Overall, the properties of the catalysts in the MCH dehydrogenation are determined by the local structure of Pt atoms rather than the crystal structure of the Pt\u2013Sn alloy nanoparticles on Al2O3.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_9_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications", "subitem_publisher_language": "en"}]}, "item_9_relation_43": {"attribute_name": "\u95a2\u9023\u60c5\u5831", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/acsanm.1c00128", "subitem_relation_type_select": "DOI"}}]}, "item_9_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "This document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Applied Nano Materials], copyright \u00a9 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-VQKNQUR8CG4KGD8HHNBF].\u201d", "subitem_rights_language": "en"}]}, "item_9_source_id_7": {"attribute_name": "\u53ce\u9332\u7269\u8b58\u5225\u5b50", "attribute_value_mlt": [{"subitem_source_identifier": "2574-0970", "subitem_source_identifier_type": "EISSN"}]}, "item_access_right": {"attribute_name": "\u30a2\u30af\u30bb\u30b9\u6a29", "attribute_value_mlt": [{"subitem_access_right": "embargoed access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_f1cf"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Murata, Kazumasa", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Kurimoto, Natsuki", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Yamamoto, Yuta", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Oda, Akira", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Ohyama, Junya", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Satsuma, Atsushi", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2022-05-28"}], "displaytype": "detail", "download_preview_message": "Download / Preview is available from 2022/5/27.", "file_order": 0, "filename": "Manuscript_20210305.pdf", "filesize": [{"value": "1.4 MB"}], "format": "application/pdf", "future_date_message": "Download is available from 2022/5/27.", "is_thumbnail": false, "mimetype": "application/pdf", "size": 1400000.0, "url": {"objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/2001679/files/Manuscript_20210305.pdf"}, "version_id": "dfd0bb05-2563-4486-896b-55315df5146b"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Pt\u2212Sn catalyst", "subitem_subject_scheme": "Other"}, {"subitem_subject": "dehydrogenation", "subitem_subject_scheme": "Other"}, {"subitem_subject": "methylcyclohexane", "subitem_subject_scheme": "Other"}, {"subitem_subject": "nanoparticle", "subitem_subject_scheme": "Other"}, {"subitem_subject": "alloy", "subitem_subject_scheme": "Other"}, {"subitem_subject": "local structure", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Structure\u2013Property Relationships of Pt\u2013Sn Nanoparticles Supported on Al2O3 for the Dehydrogenation of Methylcyclohexane", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Structure\u2013Property Relationships of Pt\u2013Sn Nanoparticles Supported on Al2O3 for the Dehydrogenation of Methylcyclohexane", "subitem_title_language": "en"}]}, "item_type_id": "40001", "owner": "17", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/0002001679", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2021-12-07"}, "publish_date": "2021-12-07", "publish_status": "0", "recid": "2001679", "relation": {}, "relation_version_is_last": true, "title": ["Structure\u2013Property Relationships of Pt\u2013Sn Nanoparticles Supported on Al2O3 for the Dehydrogenation of Methylcyclohexane"], "weko_shared_id": -1}