{"created":"2021-12-09T02:30:58.059031+00:00","id":2001699,"links":{},"metadata":{"_buckets":{"deposit":"1908eaf9-a3d7-4018-870d-c6956073ce9e"},"_deposit":{"created_by":17,"id":"2001699","owner":"17","owners":[17],"pid":{"revision_id":0,"type":"depid","value":"2001699"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:02001699","sets":["336:695:696"]},"author_link":[],"control_number":"2001699","item_1615768549627":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_1629683748249":{"attribute_name":"日付","attribute_value_mlt":[{"subitem_date_issued_datetime":"2022-04-22","subitem_date_issued_type":"Available"}]},"item_9_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021-04-22","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"15","bibliographicPageEnd":"3738","bibliographicPageStart":"3727","bibliographicVolumeNumber":"125","bibliographic_titles":[{"bibliographic_title":"The Journal of Physical Chemistry B","bibliographic_titleLang":"en"}]}]},"item_9_description_4":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"The photosynthetic pigment system on the anoxygenic type-I reaction center of heliobacteria (hRC), which has a symmetrical structure, was analyzed. The excitonic coupling among all of the bacteriochlorophyll g (BChl-g) molecules and chlorophyll a (Chl-a) molecules and the site energy for each pigment were calculated using Poisson-TrESP and the charge density coupling (CDC) methods. The obtained theoretical model reproduced the optical absorption and circular dichroism spectra. It also interpreted the decay-associated spectra upon the photoselective laser excitation, which represent the ultrafast excitation energy migration process, better than the simpler hRC models that assumed constant pigment site energy shifts. Spatial movements of excitation energy on pigments on hRC upon the laser excitation were visualized. The energy dissipation by carotenoid molecules in hRC was also predicted. The hRC model was compared with the model of the reaction center of cyanobacterial photosystem I (PSI), which carries 95 Chl-a on the analogous type-I structure with significantly different amino-acid sequences, pigment species, and output redox powers. It is shown that the locations and site energy values of pigments in hRC resemble those in the core of PSI, except for the red-Chl-a sites, suggesting common functional mechanisms implicated in their evolution.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_9_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_9_relation_43":{"attribute_name":"関連情報","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acs.jpcb.0c09400","subitem_relation_type_select":"DOI"}}]},"item_9_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This document is the Accepted Manuscript version of a Published Work that appeared in final form in [The Journal of Physical Chemistry B], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-DPQAINVRIPUEXGGCEQAF].”","subitem_rights_language":"en"}]},"item_9_source_id_7":{"attribute_name":"収録物識別子","attribute_value_mlt":[{"subitem_source_identifier":"1520-6106","subitem_source_identifier_type":"PISSN"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kimura, Akihiro","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Kitoh-Nishioka, Hirotaka","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Shigeta, Yasuteru","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Itoh, Shigeru","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-04-22"}],"displaytype":"detail","filename":"main30.pdf","filesize":[{"value":"8.5 MB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/2001699/files/main30.pdf"},"version_id":"541f5242-acbf-4daf-bb62-e40b3f66a6b1"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Comparison between the Light-Harvesting Mechanisms of Type-I Photosynthetic Reaction Centers of Heliobacteria and Photosystem I: Pigment Site Energy Distribution and Exciton State","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Comparison between the Light-Harvesting Mechanisms of Type-I Photosynthetic Reaction Centers of Heliobacteria and Photosystem I: Pigment Site Energy Distribution and Exciton State","subitem_title_language":"en"}]},"item_type_id":"40001","owner":"17","path":["696"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2021-12-09"},"publish_date":"2021-12-09","publish_status":"0","recid":"2001699","relation_version_is_last":true,"title":["Comparison between the Light-Harvesting Mechanisms of Type-I Photosynthetic Reaction Centers of Heliobacteria and Photosystem I: Pigment Site Energy Distribution and Exciton State"],"weko_creator_id":"17","weko_shared_id":-1},"updated":"2023-01-16T05:08:24.329085+00:00"}