{"_buckets": {"deposit": "9f32df0f-9f7b-41d3-bcfa-6944cd2f7f2e"}, "_deposit": {"created_by": 17, "id": "2001906", "owner": "17", "owners": [17], "owners_ext": {"displayname": "\u56f3\u66f8\u60c5\u5831\u4fc2", "username": "repository"}, "pid": {"revision_id": 0, "type": "depid", "value": "2001906"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:02001906"}, "author_link": [], "item_1615768549627": {"attribute_name": "\u51fa\u7248\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_1629683748249": {"attribute_name": "\u65e5\u4ed8", "attribute_value_mlt": [{"subitem_date_issued_datetime": "2022-08-15", "subitem_date_issued_type": "Available"}]}, "item_9_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2021-08-15", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "15", "bibliographicPageStart": "e9124", "bibliographicVolumeNumber": "35", "bibliographic_titles": [{"bibliographic_title": "Rapid Communications in Mass Spectrometry", "bibliographic_titleLang": "en"}]}]}, "item_9_description_4": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "Rationale: The triple oxygen isotopic composition (\u0394^17O) of tropospheric ozone (O3) is a useful tracer for identifying the source and is essential for clarifying the atmospheric chemistry of oxidants. However, the single nitrite-coated filter method is inaccurate owing to the nitrate blank produced through the reaction of nitrite and oxygen compounds other than O3. Methods: A multistep nitrite-coated filter-pack system is newly adopted to transfer the O-atoms in terminal positions of O3 to nitrite on each filter to determine the \u0394^17O of O3 in terminal positions (denoted as \u039417O(O3)term). The NO3^\u2212 produced by this reaction is chemically converted into N2O, and continuous-flow isotope ratio mass spectrometry (CF-IRMS) is used to determine the oxygen isotopic compositions. Results: The reciprocal of the NO3^\u2212 quantities on the nitrite-coated filters in each sample showed a strong linear relationship with \u0394^17O of NO3^\u2212. Using the linear relation, we corrected the changes in \u0394^17O of NO3^\u2212 on the filters. We verified the accuracy of the new method through the measurement of artificial O3 with known \u0394^17O(O3)term value that had been determined from the changes in \u0394^17O of O2. The \u0394^17O(O3)term of tropospheric O3 was in agreement with previous studies. Conclusions: We accurately determined the \u03b4^18O and \u0394^17O values of tropospheric O3 by blank correction using our new method. Measurements of \u0394^17O(O3)term of the ambient troposphere showed 1.1\u2009\u00b1\u20090.7\u2030 diurnal variations between daytime (higher) and nighttime (lower) due likely to the formation of the temperature inversion layer at night.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_9_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley", "subitem_publisher_language": "en"}]}, "item_9_relation_43": {"attribute_name": "\u95a2\u9023\u60c5\u5831", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/rcm.9124", "subitem_relation_type_select": "DOI"}}]}, "item_9_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [ Xu, H, Tsunogai, U, Nakagawa, F, et al. Determination of the triple oxygen isotopic composition of tropospheric ozone in terminal positions using a multistep nitrite-coated filter-pack system. Rapid Commun Mass Spectrom. 2021; 35( 15):e9124. https://doi.org/10.1002/rcm.9124], which has been published in final form at [https://doi.org/10.1002/rcm.9124]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley\u2019s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.\"", "subitem_rights_language": "en"}]}, "item_9_source_id_7": {"attribute_name": "\u53ce\u9332\u7269\u8b58\u5225\u5b50", "attribute_value_mlt": [{"subitem_source_identifier": "0951-4198", "subitem_source_identifier_type": "PISSN"}]}, "item_access_right": {"attribute_name": "\u30a2\u30af\u30bb\u30b9\u6a29", "attribute_value_mlt": [{"subitem_access_right": "embargoed access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_f1cf"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Xu, Hao", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Tsunogai, Urumu", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Nakagawa, Fumiko", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Li, Yijun", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Ito, Masanori", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Sato, Keiichi", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Tanimoto, Hiroshi", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2022-08-15"}], "displaytype": "detail", "download_preview_message": "Download / Preview is available from 2022/8/14.", "file_order": 0, "filename": "FinalFile_Xu_et_al_2021.pdf", "filesize": [{"value": "677 KB"}], "format": "application/pdf", "future_date_message": "Download is available from 2022/8/14.", "is_thumbnail": false, "mimetype": "application/pdf", "size": 677000.0, "url": {"objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/2001906/files/FinalFile_Xu_et_al_2021.pdf"}, "version_id": "76a441ef-137f-468e-a132-86a8963dddda"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Determination of the triple oxygen isotopic composition of tropospheric ozone in terminal positions using a multistep nitrite\u2010coated filter\u2010pack system", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Determination of the triple oxygen isotopic composition of tropospheric ozone in terminal positions using a multistep nitrite\u2010coated filter\u2010pack system", "subitem_title_language": "en"}]}, "item_type_id": "40001", "owner": "17", "path": ["488/489/490"], "permalink_uri": "http://hdl.handle.net/2237/0002001906", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2022-01-12"}, "publish_date": "2022-01-12", "publish_status": "0", "recid": "2001906", "relation": {}, "relation_version_is_last": true, "title": ["Determination of the triple oxygen isotopic composition of tropospheric ozone in terminal positions using a multistep nitrite\u2010coated filter\u2010pack system"], "weko_shared_id": -1}