{"_buckets": {"deposit": "3371af2e-e7f2-43a7-8ccf-7e4b3901481f"}, "_deposit": {"created_by": 17, "id": "2002046", "owner": "17", "owners": [17], "owners_ext": {"displayname": "図書情報係", "username": "repository"}, "pid": {"revision_id": 0, "type": "depid", "value": "2002046"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:02002046", "sets": ["1905"]}, "author_link": [], "control_number": "2002046", "item_1615768549627": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_1629683748249": {"attribute_name": "日付", "attribute_value_mlt": [{"subitem_date_issued_datetime": "2022-11-09", "subitem_date_issued_type": "Available"}]}, "item_9_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2021-11-09", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "21", "bibliographicPageEnd": "4940", "bibliographicPageStart": "4932", "bibliographicVolumeNumber": "363", "bibliographic_titles": [{"bibliographic_title": "Advanced Synthesis \u0026 Catalysis", "bibliographic_titleLang": "en"}]}]}, "item_9_description_4": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "We describe herein that the cross-coupling of bromodifluoroacetamides with (iodoethynyl)arenes proceeds without recourse to any photocatalyst when exposed to visible light at room temperature to afford alkynyldifluoroacetamides in 62–83% yields (27 examples). Several control experiments suggest that the reaction involves the homolysis of bromodifluoroacetamides and the coupling of the resultant difluoromethyl radical species with the 1-iodoalkynes via a radical chain process. Divergent transformations of the coupling products led to various organofluorine compounds, demonstrating the synthetic utility of the developed photo-coupling method.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_9_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Wiley", "subitem_publisher_language": "en"}]}, "item_9_relation_43": {"attribute_name": "関連情報", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/adsc.202100846", "subitem_relation_type_select": "DOI"}}]}, "item_9_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [Y. Yamamoto, E. Kuroyanagi, H. Suzuki, T. Yasui, Adv. Synth. Catal. 2021, 363, 4932.], which has been published in final form at [https://doi.org/10.1002/adsc.202100846]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.\"", "subitem_rights_language": "en"}]}, "item_9_source_id_7": {"attribute_name": "収録物識別子", "attribute_value_mlt": [{"subitem_source_identifier": "1615-4169", "subitem_source_identifier_type": "EISSN"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Yamamoto, Yoshihiko", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Kuroyanagi, Eisuke", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Suzuki, Harufumi", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Yasui, Takeshi", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2022-11-09"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "ASC_MS_Rev1.pdf", "filesize": [{"value": "9.5 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "mimetype": "application/pdf", "size": 9500000.0, "url": {"objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/2002046/files/ASC_MS_Rev1.pdf"}, "version_id": "404a6711-c095-4710-80ef-bb7ceafa3829"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Catalyst-Free Csp−Csp^3 Cross-Coupling of Bromodifluoroacetamides with 1-Iodoalkynes under Visible-Light Irradiation", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Catalyst-Free Csp−Csp^3 Cross-Coupling of Bromodifluoroacetamides with 1-Iodoalkynes under Visible-Light Irradiation", "subitem_title_language": "en"}]}, "item_type_id": "40001", "owner": "17", "path": ["1905"], "permalink_uri": "http://hdl.handle.net/2237/0002002046", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2022-02-08"}, "publish_date": "2022-02-08", "publish_status": "0", "recid": "2002046", "relation": {}, "relation_version_is_last": true, "title": ["Catalyst-Free Csp−Csp^3 Cross-Coupling of Bromodifluoroacetamides with 1-Iodoalkynes under Visible-Light Irradiation"], "weko_shared_id": -1}