{"created":"2022-02-08T04:29:41.081268+00:00","id":2002049,"links":{},"metadata":{"_buckets":{"deposit":"a987ce01-d2ca-465c-a16e-05f5986a3aaf"},"_deposit":{"created_by":17,"id":"2002049","owner":"17","owners":[17],"owners_ext":{"displayname":"図書情報係","username":"repository"},"pid":{"revision_id":0,"type":"depid","value":"2002049"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:02002049","sets":["320:321:322"]},"author_link":[],"control_number":"2002049","item_1615768549627":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_1629683748249":{"attribute_name":"日付","attribute_value_mlt":[{"subitem_date_issued_datetime":"2022-08-19","subitem_date_issued_type":"Available"}]},"item_9_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021-08-19","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"32","bibliographicPageEnd":"7700","bibliographicPageStart":"7696","bibliographicVolumeNumber":"12","bibliographic_titles":[{"bibliographic_title":"The Journal of Physical Chemistry Letters","bibliographic_titleLang":"en"}]}]},"item_9_description_4":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"The self-diffusion of a monatomic solute in liquid 1-octanol and n-tetradecane was investigated by means of a molecular dynamics simulation. The diffusion coefficient of a solute as small as argon is much greater than that obtained from the hydrodynamic-based Stokes–Einstein (SE) relation, as was reported experimentally. A relaxation of the memory function of a freely diffusing solute is much faster than that of the autocorrelation function of a shear stress. However, the SE behavior is recovered when the solute is spatially fixed, and the diffusion coefficient is calculated from the force–force autocorrelation function. A relaxation of the autocorrelation function of the force also follows that of shear stress. The fast diffusion of a small solute is thus ascribed to the decoupling between the structural relaxation of solvent and the solute diffusion induced by the self-motion of the solute.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_9_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_9_relation_43":{"attribute_name":"関連情報","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acs.jpclett.1c02219","subitem_relation_type_select":"DOI"}}]},"item_9_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This document is the Accepted Manuscript version of a Published Work that appeared in final form in [The Journal of Physical Chemistry Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-BX46GQXAIKX8TKFJQE4A].”","subitem_rights_language":"en"}]},"item_9_source_id_7":{"attribute_name":"収録物識別子","attribute_value_mlt":[{"subitem_source_identifier":"1948-7185","subitem_source_identifier_type":"EISSN"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yamaguchi, Tsuyoshi","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-08-19"}],"displaytype":"detail","filename":"sigmah2.pdf","filesize":[{"value":"652 KB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/2002049/files/sigmah2.pdf"},"version_id":"1dfd1837-6b27-4fbd-bd1c-0a71d5b878f2"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Decoupling between Solvent Viscosity and Diffusion of a Small Solute Induced by Self-Motion","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Decoupling between Solvent Viscosity and Diffusion of a Small Solute Induced by Self-Motion","subitem_title_language":"en"}]},"item_type_id":"40001","owner":"17","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2022-02-08"},"publish_date":"2022-02-08","publish_status":"0","recid":"2002049","relation_version_is_last":true,"title":["Decoupling between Solvent Viscosity and Diffusion of a Small Solute Induced by Self-Motion"],"weko_creator_id":"17","weko_shared_id":-1},"updated":"2023-01-16T05:07:16.447255+00:00"}