ログイン
言語:

WEKO3

  • トップ
  • ランキング
To
lat lon distance
To

Field does not validate



インデックスリンク

インデックスツリー

メールアドレスを入力してください。

WEKO

One fine body…

WEKO

One fine body…

アイテム

{"_buckets": {"deposit": "a3c47a93-69bd-4e41-b205-1e2f4d4e6794"}, "_deposit": {"created_by": 17, "id": "2002053", "owner": "17", "owners": [17], "owners_ext": {"displayname": "図書情報係", "username": "repository"}, "pid": {"revision_id": 0, "type": "depid", "value": "2002053"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:02002053", "sets": ["1905"]}, "author_link": [], "control_number": "2002053", "item_1615768549627": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_1629683748249": {"attribute_name": "日付", "attribute_value_mlt": [{"subitem_date_issued_datetime": "2022-09-17", "subitem_date_issued_type": "Available"}]}, "item_9_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2021-09-17", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "18", "bibliographicPageEnd": "11722", "bibliographicPageStart": "11716", "bibliographicVolumeNumber": "11", "bibliographic_titles": [{"bibliographic_title": "ACS Catalysis", "bibliographic_titleLang": "en"}]}]}, "item_9_description_4": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "Herein, we report a method for the generation of vinylallenes via cobalt/photoredox dual-catalysis-enabled formal 1,8-acyloxy migration of 1,6-diynyl esters. We demonstrated a 1,8-acyloxy migration/6π-electrocyclization cascade using (hetero)aryl-substituted 1,6-diynyl esters as substrates, leading to the formation of arenol derivatives. Several control experiments suggested that the β-oxygen elimination of a cobaltacyclopentadiene intermediate enabled formal 1,8-acyloxy migration to generate the vinylallene. We also applied this method to cascade cyclizations involving [2 + 2] or [4 + 2] cycloadditions to furnish various polycyclic molecules.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_9_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications", "subitem_publisher_language": "en"}]}, "item_9_relation_43": {"attribute_name": "関連情報", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/acscatal.1c03704", "subitem_relation_type_select": "DOI"}}]}, "item_9_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "This document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Catalysis], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-GSDTA64GIRD3EB27CCTY].”", "subitem_rights_language": "en"}]}, "item_9_source_id_7": {"attribute_name": "収録物識別子", "attribute_value_mlt": [{"subitem_source_identifier": "2155-5435", "subitem_source_identifier_type": "EISSN"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Yasui, Takeshi", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Yamada, Keiji", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Tatsumi, Rine", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Yamamoto, Yoshihiko", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2022-09-17"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "ACS_Catal-2.pdf", "filesize": [{"value": "621 KB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "mimetype": "application/pdf", "size": 621000.0, "url": {"objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/2002053/files/ACS_Catal-2.pdf"}, "version_id": "20cbd60b-37be-450b-99f6-272e5612496e"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "cobalt catalysis", "subitem_subject_scheme": "Other"}, {"subitem_subject": "metallaphotoredox", "subitem_subject_scheme": "Other"}, {"subitem_subject": "cycloaddition", "subitem_subject_scheme": "Other"}, {"subitem_subject": "allenes", "subitem_subject_scheme": "Other"}, {"subitem_subject": "cascade reaction", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Cobalt/Organophotoredox Dual-Catalysis-Enabled Cascade Cyclization of 1,6-Diynyl Esters via Formal 1,8-Acyloxy Migration", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Cobalt/Organophotoredox Dual-Catalysis-Enabled Cascade Cyclization of 1,6-Diynyl Esters via Formal 1,8-Acyloxy Migration", "subitem_title_language": "en"}]}, "item_type_id": "40001", "owner": "17", "path": ["1905"], "permalink_uri": "http://hdl.handle.net/2237/0002002053", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2022-02-08"}, "publish_date": "2022-02-08", "publish_status": "0", "recid": "2002053", "relation": {}, "relation_version_is_last": true, "title": ["Cobalt/Organophotoredox Dual-Catalysis-Enabled Cascade Cyclization of 1,6-Diynyl Esters via Formal 1,8-Acyloxy Migration"], "weko_shared_id": -1}
  1. D400 創薬科学研究科
  2. D400a 雑誌掲載論文
  3. 学術雑誌

Cobalt/Organophotoredox Dual-Catalysis-Enabled Cascade Cyclization of 1,6-Diynyl Esters via Formal 1,8-Acyloxy Migration

http://hdl.handle.net/2237/0002002053
http://hdl.handle.net/2237/0002002053
cf129537-162a-4012-a0b6-5a377e9c9890
名前 / ファイル ライセンス アクション
ACS_Catal-2.pdf ACS_Catal-2.pdf (621 KB)
Item type itemtype_ver1(1)
公開日 2022-02-08
タイトル
タイトル Cobalt/Organophotoredox Dual-Catalysis-Enabled Cascade Cyclization of 1,6-Diynyl Esters via Formal 1,8-Acyloxy Migration
言語 en
著者 Yasui, Takeshi

× Yasui, Takeshi

en Yasui, Takeshi

Search repository
Yamada, Keiji

× Yamada, Keiji

en Yamada, Keiji

Search repository
Tatsumi, Rine

× Tatsumi, Rine

en Tatsumi, Rine

Search repository
Yamamoto, Yoshihiko

× Yamamoto, Yoshihiko

en Yamamoto, Yoshihiko

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 This document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Catalysis], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-GSDTA64GIRD3EB27CCTY].”
キーワード
主題Scheme Other
主題 cobalt catalysis
キーワード
主題Scheme Other
主題 metallaphotoredox
キーワード
主題Scheme Other
主題 cycloaddition
キーワード
主題Scheme Other
主題 allenes
キーワード
主題Scheme Other
主題 cascade reaction
内容記述
内容記述 Herein, we report a method for the generation of vinylallenes via cobalt/photoredox dual-catalysis-enabled formal 1,8-acyloxy migration of 1,6-diynyl esters. We demonstrated a 1,8-acyloxy migration/6π-electrocyclization cascade using (hetero)aryl-substituted 1,6-diynyl esters as substrates, leading to the formation of arenol derivatives. Several control experiments suggested that the β-oxygen elimination of a cobaltacyclopentadiene intermediate enabled formal 1,8-acyloxy migration to generate the vinylallene. We also applied this method to cascade cyclizations involving [2 + 2] or [4 + 2] cycloadditions to furnish various polycyclic molecules.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 ACS Publications
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
関連情報
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1021/acscatal.1c03704
収録物識別子
収録物識別子タイプ EISSN
収録物識別子 2155-5435
書誌情報 en : ACS Catalysis

巻 11, 号 18, p. 11716-11722, 発行日 2021-09-17
ファイル公開日
日付 2022-09-17
日付タイプ Available
戻る
0
views
See details
Views

Versions

Ver.1 2022-02-08 06:31:58.375303
Show All versions

Share

Mendeley Twitter Facebook Print Addthis

Cite as

エクスポート

OAI-PMH
  • OAI-PMH JPCOAR
  • OAI-PMH DublinCore
  • OAI-PMH DDI
Other Formats
  • JSON
  • BIBTEX

Confirm


Powered by WEKO3


Powered by WEKO3