{"created":"2022-02-08T06:23:29.862283+00:00","id":2002053,"links":{},"metadata":{"_buckets":{"deposit":"a3c47a93-69bd-4e41-b205-1e2f4d4e6794"},"_deposit":{"created_by":17,"id":"2002053","owner":"17","owners":[17],"owners_ext":{"displayname":"図書情報係","username":"repository"},"pid":{"revision_id":0,"type":"depid","value":"2002053"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:02002053","sets":["1903:1904:1905"]},"author_link":[],"control_number":"2002053","item_1615768549627":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_1629683748249":{"attribute_name":"日付","attribute_value_mlt":[{"subitem_date_issued_datetime":"2022-09-17","subitem_date_issued_type":"Available"}]},"item_9_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021-09-17","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"18","bibliographicPageEnd":"11722","bibliographicPageStart":"11716","bibliographicVolumeNumber":"11","bibliographic_titles":[{"bibliographic_title":"ACS Catalysis","bibliographic_titleLang":"en"}]}]},"item_9_description_4":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Herein, we report a method for the generation of vinylallenes via cobalt/photoredox dual-catalysis-enabled formal 1,8-acyloxy migration of 1,6-diynyl esters. We demonstrated a 1,8-acyloxy migration/6π-electrocyclization cascade using (hetero)aryl-substituted 1,6-diynyl esters as substrates, leading to the formation of arenol derivatives. Several control experiments suggested that the β-oxygen elimination of a cobaltacyclopentadiene intermediate enabled formal 1,8-acyloxy migration to generate the vinylallene. We also applied this method to cascade cyclizations involving [2 + 2] or [4 + 2] cycloadditions to furnish various polycyclic molecules.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_9_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_9_relation_43":{"attribute_name":"関連情報","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acscatal.1c03704","subitem_relation_type_select":"DOI"}}]},"item_9_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Catalysis], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-GSDTA64GIRD3EB27CCTY].”","subitem_rights_language":"en"}]},"item_9_source_id_7":{"attribute_name":"収録物識別子","attribute_value_mlt":[{"subitem_source_identifier":"2155-5435","subitem_source_identifier_type":"EISSN"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yasui, Takeshi","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Yamada, Keiji","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Tatsumi, Rine","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Yamamoto, Yoshihiko","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-09-17"}],"displaytype":"detail","filename":"ACS_Catal-2.pdf","filesize":[{"value":"621 KB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/2002053/files/ACS_Catal-2.pdf"},"version_id":"20cbd60b-37be-450b-99f6-272e5612496e"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"cobalt catalysis","subitem_subject_scheme":"Other"},{"subitem_subject":"metallaphotoredox","subitem_subject_scheme":"Other"},{"subitem_subject":"cycloaddition","subitem_subject_scheme":"Other"},{"subitem_subject":"allenes","subitem_subject_scheme":"Other"},{"subitem_subject":"cascade reaction","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Cobalt/Organophotoredox Dual-Catalysis-Enabled Cascade Cyclization of 1,6-Diynyl Esters via Formal 1,8-Acyloxy Migration","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Cobalt/Organophotoredox Dual-Catalysis-Enabled Cascade Cyclization of 1,6-Diynyl Esters via Formal 1,8-Acyloxy Migration","subitem_title_language":"en"}]},"item_type_id":"40001","owner":"17","path":["1905"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2022-02-08"},"publish_date":"2022-02-08","publish_status":"0","recid":"2002053","relation_version_is_last":true,"title":["Cobalt/Organophotoredox Dual-Catalysis-Enabled Cascade Cyclization of 1,6-Diynyl Esters via Formal 1,8-Acyloxy Migration"],"weko_creator_id":"17","weko_shared_id":-1},"updated":"2023-01-16T04:59:03.533868+00:00"}