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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Isomerization of a cis-(2-Borylalkenyl)Gold Complex via a Retro-1,2-Metalate Shift: Cleavage of a C−C/C−Si Bond trans to a C−Au Bond

http://hdl.handle.net/2237/0002002075
http://hdl.handle.net/2237/0002002075
72fa84e8-4540-4442-8257-dbe54e995d92
名前 / ファイル ライセンス アクション
Manuscript_0715.pdf Manuscript_0715.pdf (1.5 MB)
Item type itemtype_ver1(1)
公開日 2022-02-10
タイトル
タイトル Isomerization of a cis-(2-Borylalkenyl)Gold Complex via a Retro-1,2-Metalate Shift: Cleavage of a C−C/C−Si Bond trans to a C−Au Bond
言語 en
著者 Suzuki, Akane

× Suzuki, Akane

en Suzuki, Akane

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Wu, Linlin

× Wu, Linlin

en Wu, Linlin

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Lin, Zhenyang

× Lin, Zhenyang

en Lin, Zhenyang

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Yamashita, Makoto

× Yamashita, Makoto

en Yamashita, Makoto

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 "This is the peer reviewed version of the following article: [A. Suzuki, L. Wu, Z. Lin, M. Yamashita, Angew. Chem. Int. Ed. 2021, 60, 21007.], which has been published in final form at [https://doi.org/10.1002/anie.202108530]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited."
内容記述
内容記述 This manuscript describes the first example of an alkyne insertion to the Au−B bond of a di(o-tolyl)borylgold complex to afford a cis-2-borylalkenylgold complex, and its isomerization to result in interchanging substituents on the alkenyl carbon atom and the boron atom. The former reaction is the first example of an alkyne insertion to a Au−B bond. In the latter reaction, the regiochemistry of the isomerized alkenylgold products varied depending on the substituents. DFT calculations revealed the formation of gold alkynylborates as a common intermediate via a “retro-1,2-metalate shift”, which can be considered as an anti-β-carbon/silicon elimination, and identified a subsequent 1,2-metalate shift as the regiochemistry-determining step. Relative energies of the transition states to each isomer and natural-bond-orbital (NBO) analyses were used to clearly rationalize the regiochemistry of the products.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
関連情報
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/anie.202108530
収録物識別子
収録物識別子タイプ PISSN
収録物識別子 1433-7851
書誌情報 en : Angewandte Chemie International Edition

巻 60, 号 38, p. 21007-21013, 発行日 2021-09-13
ファイル公開日
日付 2022-09-13
日付タイプ Available
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