{"_buckets": {"deposit": "beff31d8-6fce-45c1-8e22-b6039764bb00"}, "_deposit": {"created_by": 17, "id": "2002075", "owner": "17", "owners": [17], "owners_ext": {"displayname": "\u56f3\u66f8\u60c5\u5831\u4fc2", "username": "repository"}, "pid": {"revision_id": 0, "type": "depid", "value": "2002075"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:02002075", "sets": []}, "author_link": [], "control_number": "2002075", "item_1615768549627": {"attribute_name": "\u51fa\u7248\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_1629683748249": {"attribute_name": "\u65e5\u4ed8", "attribute_value_mlt": [{"subitem_date_issued_datetime": "2022-09-13", "subitem_date_issued_type": "Available"}]}, "item_9_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2021-09-13", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "38", "bibliographicPageEnd": "21013", "bibliographicPageStart": "21007", "bibliographicVolumeNumber": "60", "bibliographic_titles": [{"bibliographic_title": "Angewandte Chemie International Edition", "bibliographic_titleLang": "en"}]}]}, "item_9_description_4": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "This manuscript describes the first example of an alkyne insertion to the Au\u2212B bond of a di(o-tolyl)borylgold complex to afford a cis-2-borylalkenylgold complex, and its isomerization to result in interchanging substituents on the alkenyl carbon atom and the boron atom. The former reaction is the first example of an alkyne insertion to a Au\u2212B bond. In the latter reaction, the regiochemistry of the isomerized alkenylgold products varied depending on the substituents. DFT calculations revealed the formation of gold alkynylborates as a common intermediate via a \u201cretro-1,2-metalate shift\u201d, which can be considered as an anti-\u03b2-carbon/silicon elimination, and identified a subsequent 1,2-metalate shift as the regiochemistry-determining step. Relative energies of the transition states to each isomer and natural-bond-orbital (NBO) analyses were used to clearly rationalize the regiochemistry of the products.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_9_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley", "subitem_publisher_language": "en"}]}, "item_9_relation_43": {"attribute_name": "\u95a2\u9023\u60c5\u5831", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/anie.202108530", "subitem_relation_type_select": "DOI"}}]}, "item_9_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [A. Suzuki, L. Wu, Z. Lin, M. Yamashita, Angew. Chem. Int. Ed. 2021, 60, 21007.], which has been published in final form at [https://doi.org/10.1002/anie.202108530]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley\u2019s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.\"", "subitem_rights_language": "en"}]}, "item_9_source_id_7": {"attribute_name": "\u53ce\u9332\u7269\u8b58\u5225\u5b50", "attribute_value_mlt": [{"subitem_source_identifier": "1433-7851", "subitem_source_identifier_type": "PISSN"}]}, "item_access_right": {"attribute_name": "\u30a2\u30af\u30bb\u30b9\u6a29", "attribute_value_mlt": [{"subitem_access_right": "embargoed access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_f1cf"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Suzuki, Akane", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Wu, Linlin", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Lin, Zhenyang", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Yamashita, Makoto", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2022-09-13"}], "displaytype": "detail", "download_preview_message": "Download / Preview is available from 2022/9/12.", "file_order": 0, "filename": "Manuscript_0715.pdf", "filesize": [{"value": "1.5 MB"}], "format": "application/pdf", "future_date_message": "Download is available from 2022/9/12.", "is_thumbnail": false, "mimetype": "application/pdf", "size": 1500000.0, "url": {"objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/2002075/files/Manuscript_0715.pdf"}, "version_id": "f35f32cf-a908-401a-86b3-58e424a937ba"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Isomerization of a cis-(2-Borylalkenyl)Gold Complex via a Retro-1,2-Metalate Shift: Cleavage of a C\u2212C/C\u2212Si Bond trans to a C\u2212Au Bond", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Isomerization of a cis-(2-Borylalkenyl)Gold Complex via a Retro-1,2-Metalate Shift: Cleavage of a C\u2212C/C\u2212Si Bond trans to a C\u2212Au Bond", "subitem_title_language": "en"}]}, "item_type_id": "40001", "owner": "17", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/0002002075", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2022-02-10"}, "publish_date": "2022-02-10", "publish_status": "0", "recid": "2002075", "relation": {}, "relation_version_is_last": true, "title": ["Isomerization of a cis-(2-Borylalkenyl)Gold Complex via a Retro-1,2-Metalate Shift: Cleavage of a C\u2212C/C\u2212Si Bond trans to a C\u2212Au Bond"], "weko_shared_id": -1}