{"created":"2022-02-18T06:06:02.051144+00:00","id":2002104,"links":{},"metadata":{"_buckets":{"deposit":"6a309061-84df-4340-a940-6c0fa9230ea8"},"_deposit":{"created_by":17,"id":"2002104","owner":"17","owners":[17],"pid":{"revision_id":0,"type":"depid","value":"2002104"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:02002104","sets":["320:321:322"]},"author_link":[],"control_number":"2002104","item_1615768549627":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_1629683748249":{"attribute_name":"日付","attribute_value_mlt":[{"subitem_date_issued_datetime":"2022-07-26","subitem_date_issued_type":"Available"}]},"item_9_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021-07-26","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"7","bibliographicPageEnd":"7249","bibliographicPageStart":"7242","bibliographicVolumeNumber":"4","bibliographic_titles":[{"bibliographic_title":"ACS Applied Energy Materials","bibliographic_titleLang":"en"}]}]},"item_9_description_4":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Cu-based spinel/delafossite couples with Mn and Fe as second cations were synthesized using the Pechini method for medium-high temperature thermochemical energy storage. Physicochemical properties of each sample were investigated. Only CuMn2O4/CuMnO2 exhibited favorable redox behavior in the range of 500–1000 °C. Cu-based delafossite can reoxidize at a lower temperature (∼600 °C), which may be related to the existence of a MO6 octahedra structure. Through the isothermal oxidation method, CuMn2O4/CuMnO2 couple showed a larger oxidation enthalpy of 258.32 ± 15.31 kJ/kg (1402.68 ± 83.13 kJ/L) than 190.35 ± 4.81 kJ/kg (1048.83 ± 26.50 kJ/L) of CuFe2O4/CuFeO2 couple. CuMn2O4 was chosen for further cyclability test with 20 cycles; the depth of reduction increased gradually and stabilized at 4% change in mass after 13 cycles.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_9_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_9_relation_43":{"attribute_name":"関連情報","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acsaem.1c01352","subitem_relation_type_select":"DOI"}}]},"item_9_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This document is the Accepted Manuscript version of a Published Work that appeared in final form in [The Journal of Organic Chemistry], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-AI8V9IUEK6EKACDNGCWI].”","subitem_rights_language":"en"}]},"item_9_source_id_7":{"attribute_name":"収録物識別子","attribute_value_mlt":[{"subitem_source_identifier":"2574-0962","subitem_source_identifier_type":"EISSN"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Chen, Xiaoyu","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Kubota, Mitsuhiro","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Yamashita, Seiji","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Kita, Hideki","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-07-26"}],"displaytype":"detail","filename":"Chen-AppliedEnergyMaterials-21.pdf","filesize":[{"value":"3.4 MB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/2002104/files/Chen-AppliedEnergyMaterials-21.pdf"},"version_id":"9a7b1e5f-194e-474d-aca9-6a385eac8616"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"heat storage","subitem_subject_scheme":"Other"},{"subitem_subject":"TCES","subitem_subject_scheme":"Other"},{"subitem_subject":"medium-high temperature","subitem_subject_scheme":"Other"},{"subitem_subject":"Cu-based oxides","subitem_subject_scheme":"Other"},{"subitem_subject":"spinels","subitem_subject_scheme":"Other"},{"subitem_subject":"delafossites","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Exploring Cu-Based Spinel/Delafossite Couples for Thermochemical Energy Storage at Medium-High Temperature","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Exploring Cu-Based Spinel/Delafossite Couples for Thermochemical Energy Storage at Medium-High Temperature","subitem_title_language":"en"}]},"item_type_id":"40001","owner":"17","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2022-02-18"},"publish_date":"2022-02-18","publish_status":"0","recid":"2002104","relation_version_is_last":true,"title":["Exploring Cu-Based Spinel/Delafossite Couples for Thermochemical Energy Storage at Medium-High Temperature"],"weko_creator_id":"17","weko_shared_id":-1},"updated":"2023-01-16T04:56:53.753593+00:00"}