{"_buckets": {"deposit": "e04e9ccb-e7ee-4531-be30-99d2a385b0d2"}, "_deposit": {"created_by": 17, "id": "2003770", "owner": "17", "owners": [17], "owners_ext": {"displayname": "repository", "username": "repository"}, "pid": {"revision_id": 0, "type": "depid", "value": "2003770"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:02003770", "sets": []}, "author_link": [], "control_number": "2003770", "item_1615768549627": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_1629683748249": {"attribute_name": "日付", "attribute_value_mlt": [{"subitem_date_issued_datetime": "2023-05-18", "subitem_date_issued_type": "Available"}]}, "item_9_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2022-05-18", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "40", "bibliographicPageEnd": "5959", "bibliographicPageStart": "5956", "bibliographicVolumeNumber": "58", "bibliographic_titles": [{"bibliographic_title": "Chemical Communications", "bibliographic_titleLang": "en"}]}]}, "item_9_description_4": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "We synthesised thionium-ion embedded aromatic porphyrinoids: a free-base 5-thiaporphyrinium cation and its zinc complex. The sulphur atom effectively participates in the macrocyclic π-conjugation. Fluorescence quantum yields of thiaporphyrinium cations were lower than 1% unlike oxaporphyrinium cations. Detailed photophysical analysis and DFT calculations clarified the vibrational mode regarding the out-of-plane motion of the sulphur atom induced ultrafast quenching of the excited state in comparison to the corresponding oxaporphyrinium cations.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_9_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Royal Society of Chemistry", "subitem_publisher_language": "en"}]}, "item_9_relation_43": {"attribute_name": "関連情報", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1039/D2CC00522K", "subitem_relation_type_select": "DOI"}}]}, "item_9_source_id_7": {"attribute_name": "収録物識別子", "attribute_value_mlt": [{"subitem_source_identifier": "1359-7345", "subitem_source_identifier_type": "PISSN"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Takiguchi, Asahi", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Inai, Naoto", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Kang, Seongsoo", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Hagai, Masaya", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Lee, Seokwon", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Yanai, Takeshi", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Kim, Dongho", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Shinokubo, Hiroshi", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2023-05-18"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "OETP_09_revise.pdf", "filesize": [{"value": "826 KB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "mimetype": "application/pdf", "size": 826000.0, "url": {"objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/2003770/files/OETP_09_revise.pdf"}, "version_id": "95f4c5fd-79cb-4692-bf58-fbb4039404cc"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "5-Thiaporphyrinium cation: effect of sulphur incorporation on excited state dynamics", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "5-Thiaporphyrinium cation: effect of sulphur incorporation on excited state dynamics", "subitem_title_language": "en"}]}, "item_type_id": "40001", "owner": "17", "path": ["322"], "permalink_uri": "http://hdl.handle.net/2237/0002003770", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2022-09-13"}, "publish_date": "2022-09-13", "publish_status": "0", "recid": "2003770", "relation": {}, "relation_version_is_last": true, "title": ["5-Thiaporphyrinium cation: effect of sulphur incorporation on excited state dynamics"], "weko_shared_id": -1}