{"_buckets": {"deposit": "74e25312-2398-44ce-9523-21607d8c7c35"}, "_deposit": {"created_by": 17, "id": "2007344", "owner": "17", "owners": [17], "owners_ext": {"displayname": "repository", "username": "repository"}, "pid": {"revision_id": 0, "type": "depid", "value": "2007344"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:02007344"}, "author_link": [], "item_1615768549627": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_1629683748249": {"attribute_name": "日付", "attribute_value_mlt": [{"subitem_date_issued_datetime": "2025-03-01", "subitem_date_issued_type": "Available"}]}, "item_9_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2023-03-01", "bibliographicIssueDateType": "Issued"}, "bibliographicPageStart": "113816", "bibliographicVolumeNumber": "411-412", "bibliographic_titles": [{"bibliographic_title": "Catalysis Today", "bibliographic_titleLang": "en"}]}]}, "item_9_description_4": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "Cobalt spinel oxides, containing octahedral (Oh) and tetrahedral (Td) sites, exhibit high activity for　NO reduction by CO. The active sites of cobalt spinel oxides for NO–CO reaction was identified using various cobalt spinel oxides having different CoOh/CoTd ratio. Comparing the CoOh/CoTd ratio determined by EXAFS fitting analysis and the rate of NO reduction, it was clarified that octahedral site is responsible for NO reduction by CO. Furthermore, synchrotron-based in-situ XAFS measurements unveiled the contribution of CoOh sites: The cobalt spinel oxides with high CoOh fraction were more easily reduced by CO to form oxygen vacancies than those with low CoOh fraction, and resulted in the higher activity for NO reduction by CO.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_9_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Elsevier", "subitem_publisher_language": "en"}]}, "item_9_relation_43": {"attribute_name": "関連情報", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1016/j.cattod.2022.06.031", "subitem_relation_type_select": "DOI"}}]}, "item_9_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "© 2023. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/", "subitem_rights_language": "en"}]}, "item_9_source_id_7": {"attribute_name": "収録物識別子", "attribute_value_mlt": [{"subitem_source_identifier": "09205861", "subitem_source_identifier_type": "PISSN"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "embargoed access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_f1cf"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Ueda, Kakuya", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Tsuji, Masashi", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Ohyama, Junya", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Satsuma, Atsushi", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2025-03-01"}], "displaytype": "detail", "download_preview_message": "Download / Preview is available from 2025/2/28.", "file_order": 0, "filename": "CoSpinel-UedaSatsuma_R.pdf", "filesize": [{"value": "723 KB"}], "format": "application/pdf", "future_date_message": "Download is available from 2025/2/28.", "is_thumbnail": false, "mimetype": "application/pdf", "size": 723000.0, "url": {"objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/2007344/files/CoSpinel-UedaSatsuma_R.pdf"}, "version_id": "24c99be8-b902-4bf1-a70e-f7c9d0f3034c"}, {"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2025-03-01"}], "displaytype": "detail", "download_preview_message": "Download / Preview is available from 2025/2/28.", "file_order": 1, "filename": "CoSpinel-UedaSatsuma_Supporting.pdf", "filesize": [{"value": "224 KB"}], "format": "application/pdf", "future_date_message": "Download is available from 2025/2/28.", "is_thumbnail": false, "mimetype": "application/pdf", "size": 224000.0, "url": {"objectType": "dataset", "url": "https://nagoya.repo.nii.ac.jp/record/2007344/files/CoSpinel-UedaSatsuma_Supporting.pdf"}, "version_id": "ee8513fc-9f51-44ff-ae0f-7dc0ef1c0f2e"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Active coordination sites of Co spinel oxides for NO reduction by CO", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Active coordination sites of Co spinel oxides for NO reduction by CO", "subitem_title_language": "en"}]}, "item_type_id": "40001", "owner": "17", "path": ["322"], "permalink_uri": "http://hdl.handle.net/2237/0002007344", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2023-09-19"}, "publish_date": "2023-09-19", "publish_status": "0", "recid": "2007344", "relation": {}, "relation_version_is_last": true, "title": ["Active coordination sites of Co spinel oxides for NO reduction by CO"], "weko_shared_id": -1}