| アイテムタイプ |
itemtype_ver1(1) |
| 公開日 |
2024-05-23 |
| タイトル |
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|
タイトル |
A Triply Linked Porphyrin‐Norcorrole Hybrid with Singlet Diradical Character |
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言語 |
en |
| 著者 |
Wang, Kaisheng
Ito, Satoru
Ren, Shuang
Shimizu, Daiki
Fukui, Norihito
Kishi, Ryohei
Liu, Qiang
Osuka, Atsuhiro
Song, Jianxin
Shinokubo, Hiroshi
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| アクセス権 |
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アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 権利 |
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|
権利情報 |
"This is the peer reviewed version of the following article: [K. Wang, S. Ito, S. Ren, D. Shimizu, N. Fukui, R. Kishi, Q. Liu, A. Osuka, J. Song, H. Shinokubo, Angew. Chem. Int. Ed. 2024, 63, e202401233. https://doi.org/10.1002/anie.202401233], which has been published in final form at [https://doi.org/10.1002/anie.202401233]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited." |
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言語 |
en |
| 内容記述 |
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内容記述タイプ |
Abstract |
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内容記述 |
Norcorrole Ni(II) complexes have recently received considerable attention because they are readily accessible antiaromatic molecules. Their high stability under ambient conditions and ease of synthesis have enabled the exploration of the intrinsic properties of antiaromatic molecules. Here, we report the synthesis and properties of meso–meso singly linked porphyrin-norcorrole hybrids and a triply linked porphyrin-norcorrole hybrid. The singly linked and triply linked porphyrin-norcorrole hybrids were fully characterized, including an X-ray structural analysis. Due to their orthogonal conformation, the singly linked hybrids maintain the individual electronic properties of their porphyrin and norcorrole subunits, while the triply linked hybrid shows a significantly smaller electrochemical HOMO–LUMO gap (0.45 eV) than that of Ni(II) dimesitylnorcorrole (1.08 eV). Furthermore, the triply linked hybrid exhibits singlet diradical characteristics, as confirmed by VT NMR, ESR, and SQUID experiments. |
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言語 |
en |
| 出版者 |
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出版者 |
Wiley |
|
言語 |
en |
| 言語 |
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|
言語 |
eng |
| 資源タイプ |
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資源タイプresource |
http://purl.org/coar/resource_type/c_6501 |
|
タイプ |
journal article |
| 出版タイプ |
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出版タイプ |
AM |
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出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 関連情報 |
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|
関連タイプ |
isVersionOf |
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識別子タイプ |
DOI |
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関連識別子 |
https://doi.org/10.1002/anie.202401233 |
| 収録物識別子 |
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収録物識別子タイプ |
PISSN |
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収録物識別子 |
1433-7851 |
| 書誌情報 |
en : Angewandte Chemie International Edition
巻 63,
号 16,
p. e202401233,
発行日 2024-04-15
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| ファイル公開日 |
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日付 |
2025-04-15 |
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日付タイプ |
Available |
manuscript.pdf (3.1 MB)
