| アイテムタイプ |
itemtype_ver1(1) |
| 公開日 |
2024-05-23 |
| タイトル |
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タイトル |
Microflow Synthesis of Unsymmetrical H-Phosphonates via Sequential and Direct Substitution of Chlorine Atoms in Phosphorus Trichloride with Alkoxy Groups |
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言語 |
en |
| 著者 |
Tanaka, Yuma
Kitamura, Hiroshi
Fuse, Shinichiro
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| アクセス権 |
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アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 権利 |
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|
権利情報 |
This document is the Accepted Manuscript version of a Published Work that appeared in final form in [The Journal of Organic Chemistry], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-C4FXDC2YT8ENK8SVQQR4] |
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言語 |
en |
| 内容記述 |
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内容記述タイプ |
Abstract |
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内容記述 |
Unsymmetrical H-phosphonates were synthesized by a rapid (<15 s) and mild (20 °C) process in a microflow reactor as the first example of the sequential direct substitution of the chlorine atoms in PCl3 with alkoxyl/aryloxy groups using equivalent amounts of PCl3 and alcohols. The optimal base concentration differed in each step, presumably attributed to differences in the Brønsted basicity of the electrophilic intermediates. Phosphite hydrolysis was observed, and the structure–hydrolysis relationship was quantitatively evaluated. |
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言語 |
en |
| 出版者 |
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出版者 |
ACS Publications |
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言語 |
en |
| 言語 |
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|
言語 |
eng |
| 資源タイプ |
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資源タイプresource |
http://purl.org/coar/resource_type/c_6501 |
|
タイプ |
journal article |
| 出版タイプ |
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|
出版タイプ |
AM |
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出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 関連情報 |
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関連タイプ |
isVersionOf |
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識別子タイプ |
DOI |
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関連識別子 |
https://doi.org/10.1021/acs.joc.3c02467 |
| 収録物識別子 |
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収録物識別子タイプ |
PISSN |
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収録物識別子 |
0022-3263 |
| 書誌情報 |
en : The Journal of Organic Chemistry
巻 89,
号 3,
p. 1777-1783,
発行日 2024-02-02
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| ファイル公開日 |
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|
日付 |
2025-02-02 |
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日付タイプ |
Available |
JOC_repository.pdf (964 KB)
