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Total Synthesis of Putative Melognine
http://hdl.handle.net/2237/0002011244
http://hdl.handle.net/2237/00020112441aed5c1b-a88a-4e65-bcf0-1237b5c28787
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
20240323_irie_jacs_revision.pdf (652 KB)
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| アイテムタイプ | itemtype_ver1(1) | |||||||||
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| 公開日 | 2024-07-03 | |||||||||
| タイトル | ||||||||||
| タイトル | Total Synthesis of Putative Melognine | |||||||||
| 言語 | en | |||||||||
| 著者 |
Irie, Yui
× Irie, Yui
× Yokoshima, Satoshi
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| アクセス権 | ||||||||||
| アクセス権 | open access | |||||||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||
| 権利 | ||||||||||
| 権利情報 | This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Journal of the American Chemical Society], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-QBGCPZ7X8XAPCQTEHXPP].” | |||||||||
| 言語 | en | |||||||||
| 内容記述 | ||||||||||
| 内容記述タイプ | Abstract | |||||||||
| 内容記述 | Total synthesis of melognine was accomplished. A 10-membered cyclic alkyne was prepared via an intramolecular SN2 reaction of a nosylamide. Enyne metathesis of the cyclic alkyne under an atmosphere of ethylene afforded a 1,3-diene. Intramolecular cycloaddition of a nitrone and an azomethine ylide with the 1,3-diene moiety constructed the characteristic highly fused skeleton. Further transformation, including ring-closing metathesis, resulted in the synthesis of melognine, whose NMR spectra did not match the reported data. Close inspection of the spectra of melognine in the literature suggested that the structure of melognine might be identical with that of a known alkaloid, melodinine L. | |||||||||
| 言語 | en | |||||||||
| 出版者 | ||||||||||
| 出版者 | ACS Publications | |||||||||
| 言語 | en | |||||||||
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| 言語 | eng | |||||||||
| 資源タイプ | ||||||||||
| 資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||||||
| タイプ | journal article | |||||||||
| 出版タイプ | ||||||||||
| 出版タイプ | AM | |||||||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||
| 関連情報 | ||||||||||
| 関連タイプ | isVersionOf | |||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | https://doi.org/10.1021/jacs.4c02086 | |||||||||
| 収録物識別子 | ||||||||||
| 収録物識別子タイプ | PISSN | |||||||||
| 収録物識別子 | 0002-7863 | |||||||||
| 書誌情報 |
en : Journal of the American Chemical Society 巻 146, 号 14, p. 9526-9531, 発行日 2024-04-10 |
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| ファイル公開日 | ||||||||||
| 日付 | 2025-04-10 | |||||||||
| 日付タイプ | Available | |||||||||
