| アイテムタイプ |
itemtype_ver1(1) |
| 公開日 |
2024-10-15 |
| タイトル |
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タイトル |
Homochiral and Heterochiral Self‐Sorting Assemblies of Antiaromatic Ni(II) Norcorrole Dimers |
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言語 |
en |
| 著者 |
Liu, Si‐Yu
Li, Sha
Ukai, Shusaku
Nozawa, Ryo
Fukui, Norihito
Sugimori, Ryota
Kishi, Ryohei
Shinokubo, Hiroshi
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| アクセス権 |
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アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 権利 |
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権利情報 |
"This is the peer reviewed version of the following article: [S.-Y. Liu, S. Li, S. Ukai, R. Nozawa, N. Fukui, R. Sugimori, R. Kishi, H. Shinokubo, Chem. Eur. J. 2024, 30, e202400292. https://doi.org/10.1002/chem.202400292], which has been published in final form at [https://doi.org/10.1002/chem.202400292]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited." |
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言語 |
en |
| 内容記述 |
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内容記述タイプ |
Abstract |
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内容記述 |
Recently, π–π stacked antiaromatic π-systems have received considerable attention because they can exhibit stacked-ring aromaticity due to substantial intermolecular orbital interactions. Here, we report three antiaromatic norcorrole dimers that self-assemble to form supramolecular architectures through chiral self-sorting. A 2,2’-linked norcorrole dimer with 3,5-di-tert-butylphenyl groups forms a π-stacked dimer both in solid and solution states via homochiral self-sorting. Its association constant in solution is (3.6±1.7)×10^5 M^−1 at 20 °C. In the solid state, 3,3’-linked norcorrole dimers with 3,5-di-tert-butylphenyl and phenyl groups afford macrocyclic and helical supramolecular assemblies via heterochiral and homochiral self-sorting, respectively. Notably, the subtle modification in the substituent resulted in a complete change in the structure of the aggregates and the chiral self-sorting mode. The present findings demonstrate that structural manipulation in antiaromatic monomer units leads to the formation of various supramolecular assemblies on the basis of the attractive interactions between antiaromatic π-systems. |
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言語 |
en |
| 出版者 |
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出版者 |
Wiley |
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言語 |
en |
| 言語 |
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言語 |
eng |
| 資源タイプ |
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資源タイプresource |
http://purl.org/coar/resource_type/c_6501 |
|
タイプ |
journal article |
| 出版タイプ |
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出版タイプ |
AM |
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出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 関連情報 |
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関連タイプ |
isVersionOf |
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識別子タイプ |
DOI |
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関連識別子 |
https://doi.org/10.1002/chem.202400292 |
| 収録物識別子 |
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収録物識別子タイプ |
PISSN |
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収録物識別子 |
0947-6539 |
| 書誌情報 |
en : Chemistry – A European Journal
巻 30,
号 39,
p. e202400292,
発行日 2024-07-11
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| ファイル公開日 |
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日付 |
2025-07-11 |
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日付タイプ |
Available |
stacked_norcorrole_revised_20240520.pdf (4.4 MB)
