| アイテムタイプ |
itemtype_ver1(1) |
| 公開日 |
2024-10-15 |
| タイトル |
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|
タイトル |
Environmentally Friendly Synthesis of Polymer Nanoparticles in a Packed Reactor Using Glass Beads |
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言語 |
en |
| 著者 |
Yamamoto, Tetsuya
Morino, Ayumi
Kanda, Hideki
Seki, Ayumu
Ishigami, Toru
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| アクセス権 |
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|
アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 権利 |
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|
権利情報 |
"This is the peer reviewed version of the following article: [T. Yamamoto, A. Morino, H. Kanda, A. Seki, T. Ishigami, Environmentally Friendly Synthesis of Polymer Nanoparticles in a Packed Reactor Using Glass Beads. Macromol. React. Eng. 2024, 2400009. https://doi.org/10.1002/mren.202400009], which has been published in final form at [https://doi.org/10.1002/mren.202400009]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited." |
|
言語 |
en |
| 内容記述 |
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内容記述タイプ |
Abstract |
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内容記述 |
Polymeric particles less than 100 nm in size (polymer nanoparticles), which are useful in the fields of medicine and so on, are synthesized through emulsion polymerization, wherein surfactants are essential for maintaining their dispersion stability, contaminating particle surfaces and causing high environmental pollution. The soap-free emulsion polymerization (SFEP) of styrene in a packed reactor using microglass beads enables the synthesis of polymer nanoparticles without surfactants. Ultraviolet irradiation is used for radical polymerization using an initiator during the SFEP of styrene. The reaction space in the packed reactor is controlled by the size of glass beads to be filled in the reactor. A decrease in the size of the glass beads narrows the reaction space, causing the average polystyrene particle size to reach 27.3 nm and suppress convection flow by the wall of the glass beads, thereby limiting particle motion and preventing particle growth through particle collisions. |
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言語 |
en |
| 内容記述 |
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内容記述タイプ |
Other |
|
内容記述 |
First published: 09 May 2024 (Online Version of Record before inclusion in an issue) |
|
言語 |
en |
| 出版者 |
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出版者 |
Wiley |
|
言語 |
en |
| 言語 |
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|
言語 |
eng |
| 資源タイプ |
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資源タイプresource |
http://purl.org/coar/resource_type/c_6501 |
|
タイプ |
journal article |
| 出版タイプ |
|
|
出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 関連情報 |
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|
関連タイプ |
isVersionOf |
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|
識別子タイプ |
DOI |
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|
関連識別子 |
https://doi.org/10.1002/mren.202400009 |
| 収録物識別子 |
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|
収録物識別子タイプ |
PISSN |
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収録物識別子 |
1862-832X |
| 書誌情報 |
en : Macromolecular Reaction Engineering
巻 19,
号 1,
p. 2400009,
発行日 2025-02
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| ファイル公開日 |
|
|
日付 |
2025-05-09 |
|
日付タイプ |
Available |
packed_reactor_TI_rev4.pdf (1.2 MB)
