| アイテムタイプ |
itemtype_ver1(1) |
| 公開日 |
2025-05-19 |
| タイトル |
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タイトル |
The Latest Insights into Multiply Selective Diels–Alder Reactions Using a Chiral‐Cavity‐Structured Lewis‐Acidic Boron Catalyst |
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言語 |
en |
| 著者 |
Matsui, Kai
Toh, Kohei
Sakamoto, Tatsuhiro
Hatano, Manabu
Ishihara, Kazuaki
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| アクセス権 |
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アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 権利 |
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権利情報 |
This is the peer reviewed version of the following article: [K. Matsui, K. Toh, T. Sakamoto, M. Hatano, K. Ishihara, Adv. Synth. Catal. 2025, 367, e202401560. https://doi.org/10.1002/adsc.202401560], which has been published in final form at [https://doi.org/10.1002/adsc.202401560]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited." |
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言語 |
en |
| 内容記述 |
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内容記述タイプ |
Abstract |
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内容記述 |
The latest insights into multiply selective Diels–Alder (DA) reactions is presented, where a chiral-cavity-structured Lewis-acidic boron catalyst is employed. The catalyst ((R)-1) is capable of recognizing both dienes and dienophiles, primarily due to the influence of the suitable steric factors of its cavity. By taking advantage of the structural and exo-product-inducing properties of (R)-1, even in the presence of a mixture of inseparable dienes, the target products were successfully obtained in high yield with high enantioselectivity. As (R)-1 exhibited the capacity to differentiate between three-dimensional isomeric transition-state structures in DA reactions, this work contributes to the advancement of artificial enzyme-like catalysis, which has so far remained elusive. |
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言語 |
en |
| 出版者 |
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出版者 |
Wiley |
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言語 |
en |
| 言語 |
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言語 |
eng |
| 資源タイプ |
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資源タイプresource |
http://purl.org/coar/resource_type/c_6501 |
|
タイプ |
journal article |
| 出版タイプ |
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出版タイプ |
AM |
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出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 関連情報 |
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関連タイプ |
isVersionOf |
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識別子タイプ |
DOI |
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関連識別子 |
https://doi.org/10.1002/adsc.202401560 |
| 収録物識別子 |
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収録物識別子タイプ |
PISSN |
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収録物識別子 |
1615-4150 |
| 書誌情報 |
en : Advanced Synthesis & Catalysis
巻 367,
号 5,
p. e202401560,
発行日 2025-03-04
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| ファイル公開日 |
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日付 |
2026-03-04 |
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日付タイプ |
Available |
Manuscript.pdf (8.5 MB)
