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Synthesis of Spirocyclic Phthalans via Ru-Catalyzed [2 + 2 + 2] Cycloaddition of 1,6-Diynes with Ex-Situ Generated Acetylene
http://hdl.handle.net/2237/0002012876
http://hdl.handle.net/2237/000201287669fcbb8f-59d9-482a-9db5-887d09965229
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
3.pdf (9.5 MB)
Download is available from 2026/4/25.
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| アイテムタイプ | itemtype_ver1(1) | |||||||||||
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| 公開日 | 2025-06-12 | |||||||||||
| タイトル | ||||||||||||
| タイトル | Synthesis of Spirocyclic Phthalans via Ru-Catalyzed [2 + 2 + 2] Cycloaddition of 1,6-Diynes with Ex-Situ Generated Acetylene | |||||||||||
| 言語 | en | |||||||||||
| 著者 |
Yamamoto, Yoshihiko
× Yamamoto, Yoshihiko
× Yoshimura, Kenichi
× Yasui, Takeshi
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| アクセス権 | ||||||||||||
| アクセス権 | embargoed access | |||||||||||
| アクセス権URI | http://purl.org/coar/access_right/c_f1cf | |||||||||||
| 権利 | ||||||||||||
| 権利情報 | This document is the Accepted Manuscript version of a Published Work that appeared in final form in [The Journal of Organic Chemistry], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-BHJ578H2R8EXIEPTP8GY].” | |||||||||||
| 言語 | en | |||||||||||
| 内容記述 | ||||||||||||
| 内容記述タイプ | Abstract | |||||||||||
| 内容記述 | Spirocyclic motifs are attracting increasing attention owing to their three-dimensional geometries that endow bioactive molecules with superior physical and biological properties. We developed an efficient method for constructing spirocyclic phthalans via the Ru-catalyzed [2 + 2 + 2] cycloaddition of cycloalkanone-derived 1,6-diynes with acetylene gas ex-situ-generated from calcium carbide and H2O. | |||||||||||
| 言語 | en | |||||||||||
| 出版者 | ||||||||||||
| 出版者 | ACS Publications | |||||||||||
| 言語 | en | |||||||||||
| 言語 | ||||||||||||
| 言語 | eng | |||||||||||
| 資源タイプ | ||||||||||||
| 資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||||||||
| タイプ | journal article | |||||||||||
| 出版タイプ | ||||||||||||
| 出版タイプ | AM | |||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||
| 関連情報 | ||||||||||||
| 関連タイプ | isVersionOf | |||||||||||
| 識別子タイプ | DOI | |||||||||||
| 関連識別子 | https://doi.org/10.1021/acs.joc.5c00486 | |||||||||||
| 収録物識別子 | ||||||||||||
| 収録物識別子タイプ | PISSN | |||||||||||
| 収録物識別子 | 0022-3263 | |||||||||||
| 書誌情報 |
en : The Journal of Organic Chemistry 巻 90, 号 16, p. 5695-5703, 発行日 2025-04-25 |
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| ファイル公開日 | ||||||||||||
| 日付 | 2026-04-25 | |||||||||||
| 日付タイプ | Available | |||||||||||
