| アイテムタイプ |
itemtype_ver1(1) |
| 公開日 |
2025-06-18 |
| タイトル |
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タイトル |
Secondary nucleation as a strategy towards hierarchically organized mesoscale topologies in supramolecular polymerization |
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言語 |
en |
| 著者 |
Datta, Sougata
Itabashi, Hiroki
Saito, Takuho
Yagai, Shiki
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| アクセス権 |
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アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 権利 |
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権利情報 |
This version of the article has been accepted for publication, after peer review (when applicable) and is subject to Springer Nature’s AM terms of use, but is not the Version of Record and does not reflect post-acceptance improvements, or any corrections. The Version of Record is available online at: http://dx.doi.org/10.1038/s41557-025-01764-5 |
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言語 |
en |
| 内容記述 |
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内容記述タイプ |
Abstract |
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内容記述 |
Developing new generic methodologies for organizing molecules into nano- to mesoscale structures of precise shapes and sizes is a research topic at the forefront of modern chemistry. Creating hierarchical molecular assembly, especially at the mesoscale, is important to realize functions reminiscent of those manifested by biomolecular assemblies in the mesoscopic regime. However, this is challenging due to the difficulty in maintaining stringent controllability over the organization of molecules at higher hierarchical levels, wherein weak non-directional intermolecular interactions rather than strong directional interactions typically play a predominant role. Recent studies have revealed that secondary nucleation, often experienced by one-dimensional assemblies such as supramolecular polymers that grow with spontaneous nucleation, is effective in the hierarchical construction of higher-order structures. Here we illustrate how secondary nucleation can be combined with the well-established precision synthesis of supramolecular polymers to realize precise control over hierarchical structures in the mesoscopic regime. We present a roadmap for creating hierarchical supramolecular polymers by exploiting secondary nucleation–elongation processes and discuss future prospects for the field. |
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言語 |
en |
| 出版者 |
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出版者 |
Nature |
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言語 |
en |
| 言語 |
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|
言語 |
eng |
| 資源タイプ |
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資源タイプresource |
http://purl.org/coar/resource_type/c_6501 |
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タイプ |
journal article |
| 出版タイプ |
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出版タイプ |
AM |
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出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 関連情報 |
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関連タイプ |
isVersionOf |
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識別子タイプ |
DOI |
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関連識別子 |
https://doi.org/10.1038/s41557-025-01764-5 |
| 収録物識別子 |
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収録物識別子タイプ |
PISSN |
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収録物識別子 |
1755-4330 |
| 書誌情報 |
en : Nature Chemistry
巻 17,
p. 477-492,
発行日 2025-04
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| ファイル公開日 |
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日付 |
2025-10-01 |
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日付タイプ |
Available |
Merged_Ms-Boxes-Figures.pdf (22.8 MB)
