| アイテムタイプ |
itemtype_ver1(1) |
| 公開日 |
2025-11-27 |
| タイトル |
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タイトル |
Diruthenium(II,II) Complex Assemblies Showing Electrical Conduction via π‐Stacked 2‐Pyrenecarboxylate Moiety |
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言語 |
en |
| 著者 |
Takaki, Ren
Iguchi, Hiroaki
Qu, Liyuan
Pirillo, Jenny
Kusaka, Shinpei
Hijikata, Yuh
Tanaka, Hisaaki
Matsuda, Wakana
Seki, Shu
Matsuda, Ryotaro
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| アクセス権 |
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アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 権利 |
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権利情報 |
"This is the peer reviewed version of the following article: [R. Takaki, H. Iguchi, L. Qu, J. Pirillo, S. Kusaka, Y. Hijikata, H. Tanaka, W. Matsuda, S. Seki, R. Matsuda, Chem. Asian J. 2025, 20, e202401599. https://doi.org/10.1002/asia.202401599], which has been published in final form at [https://doi.org/10.1002/asia.202401599]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited." |
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言語 |
en |
| 内容記述 |
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内容記述タイプ |
Abstract |
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内容記述 |
Through-space electrical conduction in paddlewheel-type homovalent dinuclear complexes remains poorly understood, despite the numerous reports on these complexes. Herein, the electrical conduction of new Ru2(II,II) complexes with 2-pyrenecarboxylate (pyrCOO−) ligands, [Ru2(pyrCOO)4X2] ⋅ n(X) (where X=DMF (Ru-DMF), NMP (Ru-NMP), DMA (Ru-DMA)), was investigated. The dimensionality of π-stacking interactions between discrete molecules in Ru-DMA is higher (two-dimensional) than in Ru-DMF and Ru-NMP (stair-like one-dimensional). Nevertheless, Ru-DMF, which contains a slight amount of organic radicals, exhibited the highest electrical conductivity. This suggests that the large overlap and high dimensionality of π-stacking interactions among the complexes, along with a slight organic radical impurity, contribute to the increased electrical conductivity. |
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言語 |
en |
| 出版者 |
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出版者 |
Wiley |
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言語 |
en |
| 言語 |
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言語 |
eng |
| 資源タイプ |
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資源タイプresource |
http://purl.org/coar/resource_type/c_6501 |
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タイプ |
journal article |
| 出版タイプ |
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出版タイプ |
AM |
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出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 関連情報 |
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関連タイプ |
isVersionOf |
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識別子タイプ |
DOI |
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関連識別子 |
https://doi.org/10.1002/asia.202401599 |
| 収録物識別子 |
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収録物識別子タイプ |
PISSN |
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収録物識別子 |
1861-4728 |
| 書誌情報 |
en : Chemistry – An Asian Journal
巻 20,
号 6,
p. e202401599,
発行日 2025-03-17
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| ファイル公開日 |
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日付 |
2026-03-17 |
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日付タイプ |
Available |
Takaki_main_revision.pdf (805 KB)
