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Aldol Condensation of Bis(pentafluorophenyl)boron Enolates for the Synthesis of α-Pentafluorophenyl-Substituted α,β-Unsaturated Carbonyl Compounds
http://hdl.handle.net/2237/0002013738
http://hdl.handle.net/2237/00020137384491e4ef-73a7-4d14-a15c-b193fe1c6d17
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
OL_manuscript_rev.pdf (1.2 MB)
Download is available from 2026/9/26.
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| アイテムタイプ | itemtype_ver1(1) | |||||||||||
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| 公開日 | 2025-12-18 | |||||||||||
| タイトル | ||||||||||||
| タイトル | Aldol Condensation of Bis(pentafluorophenyl)boron Enolates for the Synthesis of α-Pentafluorophenyl-Substituted α,β-Unsaturated Carbonyl Compounds | |||||||||||
| 言語 | en | |||||||||||
| 著者 |
Yuruka, Souta
× Yuruka, Souta
× Shibuya, Masatoshi
× Yamamoto, Yoshihiko
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| アクセス権 | ||||||||||||
| アクセス権 | embargoed access | |||||||||||
| アクセス権URI | http://purl.org/coar/access_right/c_f1cf | |||||||||||
| 権利 | ||||||||||||
| 権利情報 | This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-JIS7MG8J6PZRXDJCSFXI].” | |||||||||||
| 言語 | en | |||||||||||
| 内容記述 | ||||||||||||
| 内容記述タイプ | Abstract | |||||||||||
| 内容記述 | α-Pentafluorophenyl-substituted α,β-unsaturated carbonyl compounds are valuable for synthesizing perfluoroarenes. Aldol condensation with pentafluorophenyl-substituted enolates is a highly effective method for their synthesis. This study demonstrates that bis(pentafluorophenyl)boron enolates, featuring a pentafluorophenyl group, readily undergo aldol additions with aldehydes. Subsequent elimination of borinic acid yields α-pentafluorophenyl-substituted α,β-unsaturated carbonyl compounds. Experimental results highlight the crucial role of strong Lewis acidity at the boron center in both aldol addition and borinic acid elimination. | |||||||||||
| 言語 | en | |||||||||||
| 出版者 | ||||||||||||
| 出版者 | ACS Publications | |||||||||||
| 言語 | en | |||||||||||
| 言語 | ||||||||||||
| 言語 | eng | |||||||||||
| 資源タイプ | ||||||||||||
| 資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||||||||
| タイプ | journal article | |||||||||||
| 出版タイプ | ||||||||||||
| 出版タイプ | AM | |||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||
| 関連情報 | ||||||||||||
| 関連タイプ | isVersionOf | |||||||||||
| 識別子タイプ | DOI | |||||||||||
| 関連識別子 | https://doi.org/10.1021/acs.orglett.5c03342 | |||||||||||
| 収録物識別子 | ||||||||||||
| 収録物識別子タイプ | PISSN | |||||||||||
| 収録物識別子 | 1523-7060 | |||||||||||
| 書誌情報 |
en : Organic Letters 巻 27, 号 38, p. 10733-10738, 発行日 2025-09-26 |
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| ファイル公開日 | ||||||||||||
| 日付 | 2026-09-26 | |||||||||||
| 日付タイプ | Available | |||||||||||
