| アイテムタイプ |
itemtype_ver1(1) |
| 公開日 |
2026-01-28 |
| タイトル |
|
|
タイトル |
Solvent-free isomerization of trialkoxy-heptazine derivatives featuring efficient intermolecular rearrangements |
|
言語 |
en |
| 著者 |
Dhara, Barun
Yan, Mengwen
Ibuka, Ryotaro
Wang, Jiaxian
Nihonyanagi, Atsuko
Inuzuka, Hiroyuki
Hamada, Yuko
Wakamatsu, Toshie
Adachi, Kiyohiro
Hashizume, Daisuke
Fukui, Norihito
Miyajima, Daigo
|
| アクセス権 |
|
|
アクセス権 |
embargoed access |
|
アクセス権URI |
http://purl.org/coar/access_right/c_f1cf |
| 内容記述 |
|
|
内容記述タイプ |
Abstract |
|
内容記述 |
Graphitic carbon nitrides (GCNs) have garnered broad research interest due to their potential in various applications. This study reveals a unique characteristic of heptazine, a repeating structural unit of GCN. Trialkoxy-heptazine, Hz(OR)3, undergoes nearly quantitative isomerization to trialkylheptazine-trione, HzTO-R3, under solvent-free conditions. While most quantitative isomerizations proceed intramolecularly, this isomerization occurs through intermolecular rearrangement reactions. The isomerization introduces three carbonyl groups, drastically altering the physical properties of the parent molecules and making them ideal for stimuli-responsive materials. Since this isomerization proceeds efficiently under solvent-free conditions, it can potentially be integrated into GCN-based materials, offering significant promise for the development of novel GCN-based materials and their applications. |
|
言語 |
en |
| 出版者 |
|
|
出版者 |
Elsevier |
|
言語 |
en |
| 言語 |
|
|
言語 |
eng |
| 資源タイプ |
|
|
資源タイプresource |
http://purl.org/coar/resource_type/c_6501 |
|
タイプ |
journal article |
| 出版タイプ |
|
|
出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 関連情報 |
|
|
関連タイプ |
isVersionOf |
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
https://doi.org/10.1039/d5qm00246j |
| 収録物識別子 |
|
|
収録物識別子タイプ |
EISSN |
|
収録物識別子 |
2052-1537 |
| 書誌情報 |
en : MATERIALS CHEMISTRY FRONTIERS
巻 9,
号 16,
p. 2500-2507,
発行日 2025-08-21
|
| ファイル公開日 |
|
|
日付 |
2026-08-21 |
|
日付タイプ |
Available |
Manuscript_highlighted.pdf (5 MB)
