| アイテムタイプ |
itemtype_ver1(1) |
| 公開日 |
2026-02-26 |
| タイトル |
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|
タイトル |
Acceptorless Dehydrogenative Aminoalkylation of Allylic C(sp^3)–H Bonds via Reversible Hydrogen Atom Transfer |
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言語 |
en |
| 著者 |
Minami, Kodai
Fujita, Hiroki
Ohmatsu, Kohsuke
Ooi, Takashi
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| アクセス権 |
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|
アクセス権 |
embargoed access |
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アクセス権URI |
http://purl.org/coar/access_right/c_f1cf |
| 権利 |
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|
権利情報 |
“This document is the Accepted Manuscript version of a Published Article that appeared in final form in [Organic Letters], copyright © [American Chemical Society]. To access the final published article, see [https://pubs.acs.org/articlesonrequest/AOR-IAUMJJYABW6BU5N7YBJM].” |
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言語 |
en |
| 内容記述 |
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内容記述タイプ |
Abstract |
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内容記述 |
Photoinduced acceptorless dehydrogenative cross-coupling between the benzylic C(sp^3)–H bonds of N-benzylanilines and the allylic C(sp^3)–H bonds of alkenes was developed through the combined use of an Ir-based photosensitizer, silyl thiol, and 1,2,3-triazolium amidate as catalysts. This protocol exploits the fast and reversible hydrogen atom transfer between α-aminoalkyl radicals and the silyl thiol to facilitate the cross-coupling, directly routing complex aniline derivatives from readily available, less functionalized starting materials under mild conditions. |
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言語 |
en |
| 出版者 |
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出版者 |
ACS Publications |
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言語 |
en |
| 言語 |
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|
言語 |
eng |
| 資源タイプ |
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資源タイプresource |
http://purl.org/coar/resource_type/c_6501 |
|
タイプ |
journal article |
| 出版タイプ |
|
|
出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 関連情報 |
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|
関連タイプ |
isVersionOf |
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|
識別子タイプ |
DOI |
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|
関連識別子 |
https://doi.org/10.1021/acs.orglett.5c01300 |
| 収録物識別子 |
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収録物識別子タイプ |
PISSN |
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収録物識別子 |
1523-7060 |
| 書誌情報 |
en : Organic Letters
巻 27,
号 26,
p. 6919-6923,
発行日 2025-07-04
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| ファイル公開日 |
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|
日付 |
2026-07-04 |
|
日付タイプ |
Available |
HF_OrgLett_3rdrevise_figure-retouched.pdf (813 KB)
