{"created":"2021-03-01T06:30:41.763812+00:00","id":22891,"links":{},"metadata":{"_buckets":{"deposit":"0e0e8fb1-7c54-4593-8e0b-f881751a825b"},"_deposit":{"id":"22891","owners":[],"pid":{"revision_id":0,"type":"depid","value":"22891"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00022891","sets":["1903:1904:1905"]},"author_link":["67333","67334","67335","67336"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-05-10","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"20","bibliographicPageEnd":"6070","bibliographicPageStart":"6067","bibliographicVolumeNumber":"55","bibliographic_titles":[{"bibliographic_title":"ANGEWANDTE CHEMIE-INTERNATIONAL EDITION","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Total synthesis of (−)-daphenylline, a hexacyclic Daphniphyllum alkaloid, was achieved. Construction of the tricyclic DEF ring system was initiated by asymmetric Negishi coupling followed by an intramolecular Friedel–Crafts reaction. Installation of a side chain onto the tricyclic core was carried out through Sonogashira coupling, stereocontrolled Claisen rearrangement by taking advantage of the characteristic conformation of the tricyclic DEF core, and the stereoselective alkylation of a lactone. After the introduction of a glycine unit, the ABC ring system was stereoselectively constructed through intramolecular cycloaddition of the cyclic azomethine ylide.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://doi.org/10.1002/anie.201601958"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/25060"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/anie.201601958","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: [ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. v.55, n.20, 2016, p.6067-6070], which has been published in final form at [http://doi.org/10.1002/anie.201601958]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1433-7851","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yamada, Ryosuke","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"67333","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Adachi, Yohei","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"67334","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yokoshima, Satoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"67335","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Fukuyama, Tohru","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"67336","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-05-10"}],"displaytype":"detail","filename":"20160318_daphenylline.pdf","filesize":[{"value":"1.0 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"20160318_daphenylline.pdf ファイル公開：2017-05-10","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/22891/files/20160318_daphenylline.pdf"},"version_id":"92cdc338-2412-46d5-8d07-b533e97a5d4d"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Total Synthesis of (−)-Daphenylline","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Total Synthesis of (−)-Daphenylline","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["1905"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2016-11-18"},"publish_date":"2016-11-18","publish_status":"0","recid":"22891","relation_version_is_last":true,"title":["Total Synthesis of (−)-Daphenylline"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:12:26.406084+00:00"}