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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Particle size control in the soap-free emulsion polymerization of styrene by an oil-soluble initiator with a weakly acidic water-soluble initiator

http://hdl.handle.net/2237/25076
http://hdl.handle.net/2237/25076
cd0cab53-8c0f-470b-9c9c-6e66ae4474d3
名前 / ファイル ライセンス アクション
COLLOIDS_AND_SURFACES_A_502_2016_p1.pdf COLLOIDS_AND_SURFACES_A_502_2016_p1.pdf ファイル公開:2018-08-01 (531.7 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2016-11-21
タイトル
タイトル Particle size control in the soap-free emulsion polymerization of styrene by an oil-soluble initiator with a weakly acidic water-soluble initiator
言語 en
著者 Yamamoto, Tetsuya

× Yamamoto, Tetsuya

WEKO 67374

en Yamamoto, Tetsuya

Search repository
Kawaguchi, Kan

× Kawaguchi, Kan

WEKO 67375

en Kawaguchi, Kan

Search repository
Takahashi, Yuya

× Takahashi, Yuya

WEKO 67376

en Takahashi, Yuya

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 © 2016. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
キーワード
主題Scheme Other
主題 Soap-free emulsion polymerization
キーワード
主題Scheme Other
主題 Size control
キーワード
主題Scheme Other
主題 Oil-soluble initiator
キーワード
主題Scheme Other
主題 Water-soluble initiator
抄録
内容記述 The soap-free emulsion polymerization of styrene by an oil-soluble initiator, 2,2′-azobis(2-methylpropionitrile) (AIBN), with a water-soluble initiator, 4,4′-azobis(4-cyanovaleric acid) (V-501), was conducted in water to control the size of the synthesized polymeric particles. The particle size and surface potential were monitored as concentration of V-501 used for the polymerization was varied. When the V-501 concentration was increased, the particle size increased because V-501 was a weak acid and reduced the surface potential, thereby promoting particle growth through coagulation. Additionally, V-501 can also function as a radical initiator, increasing the efficiency of the polymerization reaction and, thus, the number concentration of the particles.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 Elsevier
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1016/j.colsurfa.2016.04.048
ISSN
収録物識別子タイプ PISSN
収録物識別子 0927-7757
書誌情報 en : Colloids and Surfaces A: Physicochemical and Engineering Aspects

巻 502, p. 1-5, 発行日 2016-08
著者版フラグ
値 author
URI
識別子 http://doi.org/10.1016/j.colsurfa.2016.04.048
識別子タイプ DOI
URI
識別子 http://hdl.handle.net/2237/25076
識別子タイプ HDL
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