{"_buckets": {"deposit": "fdc688f5-e011-456e-8163-49041c29c1d2"}, "_deposit": {"id": "22897", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "22897"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00022897"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2016-08", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "5", "bibliographicPageStart": "1", "bibliographicVolumeNumber": "502", "bibliographic_titles": [{"bibliographic_title": "Colloids and Surfaces A: Physicochemical and Engineering Aspects"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The soap-free emulsion polymerization of styrene by an oil-soluble initiator, 2,2\u2032-azobis(2-methylpropionitrile) (AIBN), with a water-soluble initiator, 4,4\u2032-azobis(4-cyanovaleric acid) (V-501), was conducted in water to control the size of the synthesized polymeric particles. The particle size and surface potential were monitored as concentration of V-501 used for the polymerization was varied. When the V-501 concentration was increased, the particle size increased because V-501 was a weak acid and reduced the surface potential, thereby promoting particle growth through coagulation. Additionally, V-501 can also function as a radical initiator, increasing the efficiency of the polymerization reaction and, thus, the number concentration of the particles.", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://doi.org/10.1016/j.colsurfa.2016.04.048"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/25076"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Elsevier"}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u00a9 2016. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0927-7757", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Yamamoto, Tetsuya"}], "nameIdentifiers": [{"nameIdentifier": "67374", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kawaguchi, Kan"}], "nameIdentifiers": [{"nameIdentifier": "67375", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Takahashi, Yuya"}], "nameIdentifiers": [{"nameIdentifier": "67376", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-08-01"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "COLLOIDS_AND_SURFACES_A_502_2016_p1.pdf", "filesize": [{"value": "531.7 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 531700.0, "url": {"label": "COLLOIDS_AND_SURFACES_A_502_2016_p1.pdf \u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2018-08-01", "url": "https://nagoya.repo.nii.ac.jp/record/22897/files/COLLOIDS_AND_SURFACES_A_502_2016_p1.pdf"}, "version_id": "47222ace-fbe3-4dd2-a521-6a01625466e3"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Soap-free emulsion polymerization", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Size control", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Oil-soluble initiator", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Water-soluble initiator", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Particle size control in the soap-free emulsion polymerization of styrene by an oil-soluble initiator with a weakly acidic water-soluble initiator", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Particle size control in the soap-free emulsion polymerization of styrene by an oil-soluble initiator with a weakly acidic water-soluble initiator"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/25076", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2016-11-21"}, "publish_date": "2016-11-21", "publish_status": "0", "recid": "22897", "relation": {}, "relation_version_is_last": true, "title": ["Particle size control in the soap-free emulsion polymerization of styrene by an oil-soluble initiator with a weakly acidic water-soluble initiator"], "weko_shared_id": null}