{"created":"2021-03-01T06:30:42.158127+00:00","id":22897,"links":{},"metadata":{"_buckets":{"deposit":"fdc688f5-e011-456e-8163-49041c29c1d2"},"_deposit":{"id":"22897","owners":[],"pid":{"revision_id":0,"type":"depid","value":"22897"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00022897","sets":["320:321:322"]},"author_link":["67374","67375","67376"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-08","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"5","bibliographicPageStart":"1","bibliographicVolumeNumber":"502","bibliographic_titles":[{"bibliographic_title":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The soap-free emulsion polymerization of styrene by an oil-soluble initiator, 2,2′-azobis(2-methylpropionitrile) (AIBN), with a water-soluble initiator, 4,4′-azobis(4-cyanovaleric acid) (V-501), was conducted in water to control the size of the synthesized polymeric particles. The particle size and surface potential were monitored as concentration of V-501 used for the polymerization was varied. When the V-501 concentration was increased, the particle size increased because V-501 was a weak acid and reduced the surface potential, thereby promoting particle growth through coagulation. Additionally, V-501 can also function as a radical initiator, increasing the efficiency of the polymerization reaction and, thus, the number concentration of the particles.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://doi.org/10.1016/j.colsurfa.2016.04.048"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/25076"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.colsurfa.2016.04.048","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2016. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0927-7757","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yamamoto, Tetsuya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"67374","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kawaguchi, Kan","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"67375","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Takahashi, Yuya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"67376","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-08-01"}],"displaytype":"detail","filename":"COLLOIDS_AND_SURFACES_A_502_2016_p1.pdf","filesize":[{"value":"531.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"COLLOIDS_AND_SURFACES_A_502_2016_p1.pdf ファイル公開：2018-08-01","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/22897/files/COLLOIDS_AND_SURFACES_A_502_2016_p1.pdf"},"version_id":"47222ace-fbe3-4dd2-a521-6a01625466e3"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Soap-free emulsion polymerization","subitem_subject_scheme":"Other"},{"subitem_subject":"Size control","subitem_subject_scheme":"Other"},{"subitem_subject":"Oil-soluble initiator","subitem_subject_scheme":"Other"},{"subitem_subject":"Water-soluble initiator","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Particle size control in the soap-free emulsion polymerization of styrene by an oil-soluble initiator with a weakly acidic water-soluble initiator","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Particle size control in the soap-free emulsion polymerization of styrene by an oil-soluble initiator with a weakly acidic water-soluble initiator","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2016-11-21"},"publish_date":"2016-11-21","publish_status":"0","recid":"22897","relation_version_is_last":true,"title":["Particle size control in the soap-free emulsion polymerization of styrene by an oil-soluble initiator with a weakly acidic water-soluble initiator"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:12:35.004940+00:00"}