{"_buckets": {"deposit": "e65d0d0a-ad61-40f4-b71f-041609b4f3e2"}, "_deposit": {"id": "22898", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "22898"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00022898", "sets": ["322"]}, "author_link": ["67377", "67378", "67379", "67380", "67381", "67382", "67383"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2016-05-03", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "11", "bibliographicPageEnd": "1594", "bibliographicPageStart": "1885", "bibliographicVolumeNumber": "35", "bibliographic_titles": [{"bibliographic_title": "Organometallics", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "We describe the preparation and catalytic reactions of new CCN pincer Rh and Ru complexes containing NCH-oxazoline hybrid ligands. Oxazolinyl-phenyl-imidazolium derivatives (3) were suitable ligand precursors for the CCN pincer scaffold. C–H bond activation of 3 with RhCl3·3H2O in the presence of NEt3 yielded the desired CCN pincer Rh complexes 5 in 13–27% yields. The related CCN pincer Ru complexes 8–10 were synthesized in good yields by C–H bond activation of p-cymene Ru complexes 7 in the presence of NaOAc in DMF. The chiral complexes 8 and 9 had two diastereomers according to the coordination of CO and OAc ligands. The CCN Rh complexes showed catalytic activity for conjugate reduction of ethyl β-methylcinnamate with hydrosilane, with moderate enantioselectivity. The CCN Ru complexes were found to be active in the hydrogenation of aromatic ketones. In particular, hydrogenation of 9-acetylanthracene took place at not only the C═O bond but also the anthracene ring. The Ru complexes were also used as catalysts in the transfer hydrogenation of 9-acetylanthracene with 2-propanol; again, both the C═O bond and the anthracene ring were hydrogenated.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://doi.org/10.1021/acs.organomet.6b00239"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/25077"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/acs.organomet.6b00239", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/doi/abs/10.1021/acs.organomet.6b00239].”", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0276-7333", "subitem_source_identifier_type": "PISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Ito, Jun-ichi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "67377", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sugino, Kanae", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "67378", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Matsushima, Satoru", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "67379", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sakaguchi, Hiroki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "67380", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Iwata, Hiroshi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "67381", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ishihara, Takahiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "67382", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nishiyama, Hisao", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "67383", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-05-03"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "OA.pdf", "filesize": [{"value": "1.1 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 1100000.0, "url": {"label": "OA.pdf ファイル公開:2017-05-03", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/22898/files/OA.pdf"}, "version_id": "96528cd2-4500-4ded-bc15-852823b677c2"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis of NHC-Oxazoline Pincer Complexes of Rh and Ru and Their Catalytic Activity for Hydrogenation and Conjugate Reduction", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Synthesis of NHC-Oxazoline Pincer Complexes of Rh and Ru and Their Catalytic Activity for Hydrogenation and Conjugate Reduction", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["322"], "permalink_uri": "http://hdl.handle.net/2237/25077", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2016-11-22"}, "publish_date": "2016-11-22", "publish_status": "0", "recid": "22898", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis of NHC-Oxazoline Pincer Complexes of Rh and Ru and Their Catalytic Activity for Hydrogenation and Conjugate Reduction"], "weko_shared_id": -1}