@article{oai:nagoya.repo.nii.ac.jp:00022898, author = {Ito, Jun-ichi and Sugino, Kanae and Matsushima, Satoru and Sakaguchi, Hiroki and Iwata, Hiroshi and Ishihara, Takahiro and Nishiyama, Hisao}, issue = {11}, journal = {Organometallics}, month = {May}, note = {We describe the preparation and catalytic reactions of new CCN pincer Rh and Ru complexes containing NCH-oxazoline hybrid ligands. Oxazolinyl-phenyl-imidazolium derivatives (3) were suitable ligand precursors for the CCN pincer scaffold. C–H bond activation of 3 with RhCl3·3H2O in the presence of NEt3 yielded the desired CCN pincer Rh complexes 5 in 13–27% yields. The related CCN pincer Ru complexes 8–10 were synthesized in good yields by C–H bond activation of p-cymene Ru complexes 7 in the presence of NaOAc in DMF. The chiral complexes 8 and 9 had two diastereomers according to the coordination of CO and OAc ligands. The CCN Rh complexes showed catalytic activity for conjugate reduction of ethyl β-methylcinnamate with hydrosilane, with moderate enantioselectivity. The CCN Ru complexes were found to be active in the hydrogenation of aromatic ketones. In particular, hydrogenation of 9-acetylanthracene took place at not only the C═O bond but also the anthracene ring. The Ru complexes were also used as catalysts in the transfer hydrogenation of 9-acetylanthracene with 2-propanol; again, both the C═O bond and the anthracene ring were hydrogenated.}, pages = {1885--1594}, title = {Synthesis of NHC-Oxazoline Pincer Complexes of Rh and Ru and Their Catalytic Activity for Hydrogenation and Conjugate Reduction}, volume = {35}, year = {2016} }